57728-86-6

Basic information

• Product Name: Methanesulfonic acid, trifluoro-, 4-(methylsulfonyl)phenyl ester
• CAS NO: 57728-86-6
• Molecular Formula: C8H7F3O5S2
• Molecular Weight: 304.268
• Mol File: 57728-86-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Methanesulfonic acid, trifluoro-, 4-(methylsulfonyl)phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Methanesulfonic acid, trifluoro-, 4-(methylsulfonyl)phenyl ester(57728-86-6)
• EPA Substance Registry System: Methanesulfonic acid, trifluoro-, 4-(methylsulfonyl)phenyl ester(57728-86-6)

Safety Data

• Hazardous Substances Data: 57728-86-6(Hazardous Substances Data)

Upstream product

• 1493-13-6 trifluorormethanesulfonic acid 
• 14763-60-1 4-methanesulfonyl-phenol 
• 66107-30-0 4-bromophenyl trifluoromethanesulfonate 
• 17763-67-6 Phenyl triflate 
• 109586-39-2 4-iodophenyl trifluoromethanesulfonate 
• 7143-01-3 Methanesulfonic anhydride 

Downstream Products

• 6274-54-0 methylsulfonyl-4 benzoate d'ethyle 
• 80819-01-8 4-(methylsulfonyl)-N-(pyridin-4-ylmethyl)benzamide 
• 4052-30-6 4-methylsulfonylbenzoic acid 
• 22821-76-7 4-(methylsulfonyl)benzonitrile 
• 5398-77-6 para-methanesulfonylbenzaldehyde 

Relevant articles and documents

Ni-Catalyzed Cross-Electrophile Coupling of Aryl Triflates with Thiocarbonates via C-O/C-O Bond Cleavage

A nickel-catalyzed reductive coupling of aryl triflates with thiocarbonates is reported here. Both electron-rich and -deficient aryl C(sp2)-O electrophiles as well as a class of O-tBu S-alkyl thiocarbonates are compatible with the optimized reaction conditions, as evidenced by 49 examples. The reaction also proceeds with good chemoselective cleavage of the C-O bond with regard to thioesters. This work broadens the scope of nickel-catalyzed reductive cross-electrophile coupling reactions.

Perfluoroalkanesulfonate ester herbicides

Perfluoroalkanesulfonate esters of methyl- thio-, methylsulfinyl- or methylsulfonyl-substituted phenols. The compounds are herbicides.