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58041-19-3

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58041-19-3 Usage

General Description

2,3-Dihydro-5,6-diphenyl-1,4-oxathin is a chemical compound with the molecular formula C18H16OS. It is a heterocyclic compound that contains a six-membered ring with an oxygen and a sulfur atom. 2,3-DIHYDRO-5,6-DIPHENYL-1,4-OXATHIIN is commonly used as a building block in organic synthesis and as a research reagent. It is also known for its potential applications in pharmaceuticals, agrochemicals, and materials science. It is important to handle this compound with care as it may pose hazards to human health and the environment if not properly managed.

Check Digit Verification of cas no

The CAS Registry Mumber 58041-19-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,8,0,4 and 1 respectively; the second part has 2 digits, 1 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 58041-19:
(7*5)+(6*8)+(5*0)+(4*4)+(3*1)+(2*1)+(1*9)=113
113 % 10 = 3
So 58041-19-3 is a valid CAS Registry Number.
InChI:InChI=1/C16H14OS/c1-3-7-13(8-4-1)15-16(18-12-11-17-15)14-9-5-2-6-10-14/h1-10H,11-12H2

58041-19-3 Well-known Company Product Price

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  • Aldrich

  • (D2015)  2,3-Dihydro-5,6-diphenyl-1,4-oxathiin  

  • 58041-19-3

  • D2015-25G

  • 865.80CNY

  • Detail

58041-19-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 5,6-diphenyl-2,3-dihydro-1,4-oxathiine

1.2 Other means of identification

Product number -
Other names 1,4-OXATHIIN,2,3-DIHYDRO-5,6-DIPHENYL

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:58041-19-3 SDS

58041-19-3Synthetic route

2-(Bromo-phenyl-methyl)-2-phenyl-[1,3]oxathiolane
101249-26-7

2-(Bromo-phenyl-methyl)-2-phenyl-[1,3]oxathiolane

5,6-diphenyl-2,3-dihydro-1,4-oxathiin
58041-19-3

5,6-diphenyl-2,3-dihydro-1,4-oxathiin

Conditions
ConditionsYield
With potassium tert-butylate In dimethyl sulfoxide for 0.5h;85%
2-benzyl-2-phenyl-[1,3]oxathiolane
130987-41-6

2-benzyl-2-phenyl-[1,3]oxathiolane

5,6-diphenyl-2,3-dihydro-1,4-oxathiin
58041-19-3

5,6-diphenyl-2,3-dihydro-1,4-oxathiin

Conditions
ConditionsYield
With tellurium tetrachloride In dichloromethane for 0.5h; Ambient temperature;39%
α-(2-hydroxy-ethylsulfanyl)-deoxybenzoin
101169-01-1

α-(2-hydroxy-ethylsulfanyl)-deoxybenzoin

5,6-diphenyl-2,3-dihydro-1,4-oxathiin
58041-19-3

5,6-diphenyl-2,3-dihydro-1,4-oxathiin

Conditions
ConditionsYield
With toluene-4-sulfonic acid; toluene Unter Entfernen des entstehenden Wassers;
2-hydroxy-2-phenylacetophenone
119-53-9

2-hydroxy-2-phenylacetophenone

2-hydroxyethanethiol
60-24-2

2-hydroxyethanethiol

A

5,6-diphenyl-2,3-dihydro-1,4-oxathiin
58041-19-3

5,6-diphenyl-2,3-dihydro-1,4-oxathiin

B

phenyl-(2-phenyl-[1,3]oxathiolan-2-yl)-methanol
101169-04-4

phenyl-(2-phenyl-[1,3]oxathiolan-2-yl)-methanol

Conditions
ConditionsYield
With toluene-4-sulfonic acid; toluene
2-hydroxy-2-phenylacetophenone
119-53-9

2-hydroxy-2-phenylacetophenone

2-hydroxyethanethiol
60-24-2

2-hydroxyethanethiol

5,6-diphenyl-2,3-dihydro-1,4-oxathiin
58041-19-3

5,6-diphenyl-2,3-dihydro-1,4-oxathiin

Conditions
ConditionsYield
acid
2-hydroxy-2-phenylacetophenone
119-53-9

2-hydroxy-2-phenylacetophenone

2-hydroxyethanethiol
60-24-2

2-hydroxyethanethiol

A

5,6-diphenyl-2,3-dihydro-1,4-oxathiin
58041-19-3

5,6-diphenyl-2,3-dihydro-1,4-oxathiin

B

phenyl-<2-phenyl-<1,3>oxathiolan-2-yl>-methanol

phenyl-<2-phenyl-<1,3>oxathiolan-2-yl>-methanol

Conditions
ConditionsYield
With toluene-4-sulfonic acid; toluene Unter Entfernen des entstehenden Wassers;
Desyl chloride
447-31-4

Desyl chloride

5,6-diphenyl-2,3-dihydro-1,4-oxathiin
58041-19-3

5,6-diphenyl-2,3-dihydro-1,4-oxathiin

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: ethanolic NaOH
2: toluene; toluene-4-sulfonic acid / Unter Entfernen des entstehenden Wassers
View Scheme
phenyl benzyl ketone
451-40-1

phenyl benzyl ketone

2-hydroxyethanethiol
60-24-2

2-hydroxyethanethiol

5,6-diphenyl-2,3-dihydro-1,4-oxathiin
58041-19-3

5,6-diphenyl-2,3-dihydro-1,4-oxathiin

Conditions
ConditionsYield
With hydrogenchloride; sulfuryl dichloride; toluene-4-sulfonic acid In benzene
5,6-diphenyl-2,3-dihydro-1,4-oxathiin
58041-19-3

5,6-diphenyl-2,3-dihydro-1,4-oxathiin

2,3-Dihydro-5,6-diphenyl-1,4-oxathiin 4-oxide

2,3-Dihydro-5,6-diphenyl-1,4-oxathiin 4-oxide

Conditions
ConditionsYield
With dihydrogen peroxide In water; acetic acid88%
5,6-diphenyl-2,3-dihydro-1,4-oxathiin
58041-19-3

5,6-diphenyl-2,3-dihydro-1,4-oxathiin

1,6-Diphenyl-2,7,8-trioxa-5-thia-bicyclo[4.2.0]octane
99218-00-5

1,6-Diphenyl-2,7,8-trioxa-5-thia-bicyclo[4.2.0]octane

Conditions
ConditionsYield
With polystirene-immobilized Rose Bengal In dichloromethane Irradiation;
5,6-diphenyl-2,3-dihydro-1,4-oxathiin
58041-19-3

5,6-diphenyl-2,3-dihydro-1,4-oxathiin

2-(benzoylthio)ethyl benzoate
1226-99-9

2-(benzoylthio)ethyl benzoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: polystirene-immobilized Rose Bengal / CH2Cl2 / Irradiation
2: DBA / o-xylene / 70 - 90.3 °C
View Scheme
5,6-diphenyl-2,3-dihydro-1,4-oxathiin
58041-19-3

5,6-diphenyl-2,3-dihydro-1,4-oxathiin

2,3-Dihydro-5,6-diphenyl-1,4-oxathiin 4,4-dioxide

2,3-Dihydro-5,6-diphenyl-1,4-oxathiin 4,4-dioxide

Conditions
ConditionsYield
With formic acid; dihydrogen peroxide In toluene
5,6-diphenyl-2,3-dihydro-1,4-oxathiin
58041-19-3

5,6-diphenyl-2,3-dihydro-1,4-oxathiin

C10H10O3S

C10H10O3S

Conditions
ConditionsYield
With 5-(4-hydroxyphenyl)-10,15,20-triphenylporphyrin for 1h; Irradiation; Atmospheric conditions;99 %Chromat.

58041-19-3Relevant articles and documents

Ring Expansion Reaction of 1,3-Dithiolanes and 1,3-Oxathiolanes Using Tellurium Tetrachloride

Tani, Hiroyuki,Inamasu, Tokuo,Tamura, Rui,Suzuki, Hitomi

, p. 1323 - 1326 (2007/10/02)

On treatment with tellurium tetrachloride in dichloromethane at room temperature, 1,3-dithiolanes and 1,3-oxathiolanes undergo smooth ring expansion to give dihydro-1,4-dithiin and dihydro-1,4-oxathiin derivatives respectively in good to moderate yields.

EFFECTS OF HETEROATOM SUBSTITUENTS ON THE PROPERTIES OF 1,2-DIOXETANES

Handley, Richard S.,Stern, Alan J.,Schaap, A. Paul

, p. 3183 - 3186 (2007/10/02)

Nitrogen and sulfur-substituted dioxetanes exhibit dramatically lower activation energies for decomposition compared to the corresponding oxygen-bearing dioxetane.A mechanism involving intramolecular electron-transfer processes is proposed for the cleavage of these unstable dioxetanes.

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