58187-85-2

Basic information

• Product Name: Benzene, 1-(3-bromo-1-propenyl)-2-chloro-
• CAS NO: 58187-85-2
• Molecular Formula: C9H8BrCl
• Molecular Weight: 231.52
• Mol File: 58187-85-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(3-bromo-1-propenyl)-2-chloro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(3-bromo-1-propenyl)-2-chloro-(58187-85-2)
• EPA Substance Registry System: Benzene, 1-(3-bromo-1-propenyl)-2-chloro-(58187-85-2)

Safety Data

• Hazardous Substances Data: 58187-85-2(Hazardous Substances Data)

Upstream product

• 1504-71-8 3-(2-chlorophenyl)prop-2-en-1-ol 

Downstream Products

• 1202576-49-5 (-)-(S)-5-(1-(2-chlorophenyl)allyl)-1,3-benzodioxole 
• 1202576-34-8 (-)-(S)-1-chloro-2-(1-phenylallyl)benzene 
• 28010-12-0 5-phenylpenta-2,4-dienoic acid 
• 15542-32-2 (2E,4E)-5-(2-chlorophenyl)penta-2,4-dienoic acid 

Relevant articles and documents

N-heterocyclic carbene-mediated oxidative esterification of aldehydes: Ester formation and mechanistic studies

An unexpected N-heterocyclic carbene-catalyzed esterification of α,β-unsaturated aldehydes including aromatic aldehydes with reactive cinnamyl bromides in the presence of air oxygen or MnO2 as an oxidant is described. In the presence of oxygen, halogenated and electron-deficient aldehydes react smoothly to furnish esters in good yields. Great efforts have been made on mechanistic studies to deduce a plausible mechanism, based on the experimental results and isotopic labeling experiment.