58210-04-1Relevant articles and documents
Deracemization of bilirubin as the marker of the chirality of micellar aggregates
Sorrenti, Alessandro,Altieri, Barbara,Ceccacci, Francesca,Di Profio, Pietro,Germani, Raimondo,Giansanti, Luisa,Savelli, Gianfranco,Mancini, Giovanna
experimental part, p. 78 - 85 (2012/03/26)
The deracemization of bilirubin in micellar aggregates of structurally correlated chiral surfactants was studied by circular dichroism experiments and exploited as the marker of the expression of chirality of the aggregates. The obtained results suggest that the hydrophobic interactions control the transfer of chirality from the monomers to the aggregates, and that different regions of the same aggregate might feature opposite enantiorecognition capabilities.
New chiral ligand for optically active β-Hydroxy esters synthesis by enantioselective reformatsky reactions
Pini,Mastantuono,Salvadori
, p. 1875 - 1876 (2007/10/02)
The cheap commercially available (1S,2S)-1-phenyl-2-amino-1,3-propanediol 2 appears to be a convenient precursor for the synthesis of chiral auxiliaries for the preparation of optically active P-hydroxy esters by asymmetric Reformatsky reactions. The N,N-
