58280-04-9

Basic information

• Product Name: (4-benzylphenyl)(phenyl)methanone
• Synonyms: (4-benzylphenyl)(phenyl)methanone
• CAS NO: 58280-04-9
• Molecular Weight: 272.346
• Mol File: 58280-04-9.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: (4-benzylphenyl)(phenyl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: (4-benzylphenyl)(phenyl)methanone(58280-04-9)
• EPA Substance Registry System: (4-benzylphenyl)(phenyl)methanone(58280-04-9)

Safety Data

• Hazardous Substances Data: 58280-04-9(Hazardous Substances Data)

Upstream product

• 3016-97-5 1,4-dibenzoylbenzene 
• 101-81-5 Diphenylmethane 
• 98-88-4 benzoyl chloride 
• 1619239-53-0 1-(4-benzoylbenzyl)tetrahydro-1H-thiophen-1-ium tetraphenylborate 
• 32752-54-8 4-(bromomethyl)benzophenone 
• 793-23-7 1,4-dibenzylbenzene 
• 108-94-1 cyclohexanone 
• 82639-40-5 p-benzylbenzohydrol 
• 100-44-7 benzyl chloride 
• 134-85-0 4-chlorobenzophenone 
• 876-08-4 p-(chloromethyl)benzoyl chloride 
• 98-80-6 phenylboronic acid 
• 71-43-2 benzene 
• 31688-74-1 p-PhC(O)C₆H₄NMe₃(+)*I(-) 

Downstream Products

• 82639-41-6 bis<α-(p-benzylphenyl)benzyl>ether 
• 82639-42-7 α,α'-diphenyl-α-bromo-p-xylene 
• 643001-27-8 [4-(bromo-phenyl-methyl)-phenyl]-phenyl-methanone 
• 3016-97-5 1,4-dibenzoylbenzene 
• 82639-40-5 p-benzylbenzohydrol 
• 56430-97-8 4-Benzyl-α-ethyl-benzhydrol 

Relevant articles and documents

Selective electrochemical oxidation of aromatic hydrocarbons and preparation of mono/multi-carbonyl compounds

A selective electrochemical oxidation was developed under mild condition. Various mono-carbonyl and multi-carbonyl compounds can be prepared from different aromatic hydrocarbons with moderate to excellent yield and selectivity by virtue of this electrochemical oxidation. The produced carbonyl compounds can be further transformed into α-ketoamides, homoallylic alcohols and oximes in a one-pot reaction. In particular, a series of α-ketoamides were prepared in a one-pot continuous electrolysis. Mechanistic studies showed that 2,2,2-trifluoroethan-1-ol (TFE) can interact with catalyst species and generate the corresponding hydrogen-bonding complex to enhance the electrochemical oxidation performance. [Figure not available: see fulltext.]

Method for preparing epsilon-caprolactone by using in-situ peroxide

The invention discloses a method for preparing epsilon-caprolactone by using in-situ peroxide. The method efficiently utilizes an in-situ peroxide obtained in a process of oxidizing alcohol by oxygento oxidize cyclohexanone into epsilon-caprolactone, i.e., under the catalysis of a catalyst, an alcohol is oxidized into the corresponding ketone while substances such as peroxy hydroxyl or hydrogen peroxide and the like generated in the process are fully utilized, so that the Baeyer Villiger oxidation reaction from cyclohexanone to epsilon-caprolactone is realized. Compared with a previous epsilon-caprolactone synthesis method, the method of the invention has the advantages that the product yield is remarkably increased, the use efficiency of alcohol is further improved, raw materials and reagents are cheap and easy to obtain, operation is easy, reaction conditions are mild, and the method is clean and environmentally friendly.

Metal-free carbon-carbon cross-couplings between the ion pairs in sulfonium tetraphenylborates

A series of sulfonium tetraphenylborates can be readily prepared by the metathesis of sulfonium halides with sodium tetraphenylborates. After heating at 120-150 °C, the sulfonium tetraphenylborates can smoothly undergo the cross-couplings between the tetraphenylborate anions and the sulfonium cations in the absence of a metal catalyst. For carbonylmethyl-, benzyl-, and allylsulfoniums, the corresponding carbonylmethyl-phenyl, benzyl-phenyl, and allyl-phenyl cross-coupling products can be obtained in 22-76% yields. An interionic electron-transfer mechanism for this cross-coupling reaction is proposed.