58324-87-1

Basic information

• Product Name: 3,5-bis(tri?uoromethyl)phenyl phenyl sulfide
• Synonyms: 3,5-bis(tri?uoromethyl)phenyl phenyl sulfide
• CAS NO: 58324-87-1
• Molecular Weight: 322.274
• Mol File: 58324-87-1.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 3,5-bis(tri?uoromethyl)phenyl phenyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-bis(tri?uoromethyl)phenyl phenyl sulfide(58324-87-1)
• EPA Substance Registry System: 3,5-bis(tri?uoromethyl)phenyl phenyl sulfide(58324-87-1)

Safety Data

• Hazardous Substances Data: 58324-87-1(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 591-50-4 iodobenzene 
• 130783-02-7 3,5-bis(trifluoromethyl)thiophenol 
• 328-73-4 3,5-bis(trifluoromethyl)iodobenzene 
• 73852-19-4 3,5-bis-trifluromethylphenylboronic acid 
• 931-59-9 benzenesulfenyl chloride 
• 402-31-3 1,3-bis(trifluoromethyl)benzene 
• 328-70-1 3,6-bis(trifluoromethyl)bromobenzene 
• 882-33-7 diphenyldisulfane 
• 328-75-6 1-nitro-3,5-bis(trifluoromethyl)benzene 
• 930-69-8 sodium thiophenolate 

Relevant articles and documents

Dimsyl Anion Enables Visible-Light-Promoted Charge Transfer in Cross-Coupling Reactions of Aryl Halides

A methodology is reported for visible-light-promoted synthesis of unsymmetrical chalcogenides enabled by dimsyl anion in the absence of transition-metals or photoredox catalysts. The cross-coupling reaction between aryl halides and diaryl dichalcogenides proceeds with electron-rich, electron-poor, and heteroaromatic moieties. Mechanistic investigations using UV-Vis spectroscopy, time-dependent density functional theory (TD-DFT) calculations, and control reactions suggest that dimsyl anion forms an electron-donor-acceptor (EDA) complex capable of absorbing blue light, leading to a charge transfer responsible for generation of aryl radicals from aryl halides. This previously unreported mechanistic pathway may be applied to other light-induced transformations performed in DMSO in the presence of bases and aryl halides.

New arylselanylpyrazole-copper catalysts: Highly efficient catalytic system for C–Se and C–S coupling reactions

We describe herein the use of arylselanylpyrazole–copper complexes as versatile catalysts for C–Se and C–S coupling reactions. The performance of these complexes for C–Se reactions was investigated in chalcogenoacetylene synthesis. The reactions were carried out under mild and aerobic conditions and afforded selanylalkynes bearing a variety of electron-withdrawing and electron-donating groups. The performance of these catalysts for C–S coupling was investigated through the reaction of aryl halides with thiols and products were obtained in moderate to excellent yields. A plausible mechanism for selenoacetylene synthesis is also suggested, and the 77Se NMR results show that these arylselanylpyrazole ligands act as hemilabile ligands. High-resolution mass spectrometry was used to investigate the intermediates and also to corroborate the proposed catalytic cycle.

Microwave-assisted efficient synthesis of aryl thioethers through C-H functionalization of arenes

Microwave-assisted iridium-catalyzed meta C-H borylation followed by copper-promoted C-S bond coupling reactions in one pot is reported. This approach enables the syntheses of aryl thioethers in short reaction times (within 2.5 hours). The system shows go