58329-99-0

Basic information

• Product Name: Carbonic acid, 2-cyclohexen-1-yl methyl ester
• Synonyms: methyl cyclohex-2-enyl carbonate;methyl cyclohex-2-en-1-yl carbonate;cyclohex-2-en-1-yl methyl carbonate;cyclohex-2-enyl methyl carbonate;(+/-)-cyclohex-2-enyl methyl carbonate;methyl (+/-)-(cyclohex-2-enyl) carbonate
• CAS NO: 58329-99-0
• Molecular Formula: C8H12O3
• Molecular Weight: 156.181
• Mol File: 58329-99-0.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 240.6±20.0 °C(Predicted)
• Density: 1.06±0.1 g/cm3(Predicted)
• CAS DataBase Reference: Carbonic acid, 2-cyclohexen-1-yl methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbonic acid, 2-cyclohexen-1-yl methyl ester(58329-99-0)
• EPA Substance Registry System: Carbonic acid, 2-cyclohexen-1-yl methyl ester(58329-99-0)

Safety Data

• Hazardous Substances Data: 58329-99-0(Hazardous Substances Data)

Upstream product

• 822-67-3 Cyclohex-2-enol 
• 616-38-6 carbonic acid dimethyl ester 
• 79-22-1 methyl chloroformate 
• 124-41-4 sodium methylate 
• 110-83-8 cyclohexene 

Downstream Products

• 86769-68-8 methyl 2,2-dimethyl-2-(2'-cyclohexen-1'-yl)acetate 
• 6426-26-2 (S)-cyclohex-2-en-1-ol 
• 171868-69-2 (S)-(cyclohex-2-en-1-ylsulfonyl)benzene 
• 219525-40-3 (R)-carbonic acid cyclohex-2-enyl methyl ester 
• 17540-19-1 (+)-(R)-3-phenylcyclohexene 
• 17540-19-1 (–)-(S)-cyclohex-2-enylbenzene 

Relevant articles and documents

Intramolecular Sakurai Allylation of Geminal Bis(silyl) Enamide with Indolenine. A Diastereoselective Cyclization to Form Functionalized Hexahydropyrido[3,4- b]Indole

A fluoride-promoted intramolecular Sakurai allylation of geminal bis(silyl) enamide with indolenine has been developed. The reaction facilitates an efficient cyclization to give hexahydropyrido[3,4-b]indoles in good yields with high diastereoselectivity. The resulted cis, trans-stereochemistry further enables the ring-closing metathesis (RCM) reaction of two alkene moieties, giving a tetracyclic N-hetereocycle widely found as the core structure in akuammiline alkaloids.

Sustainable Palladium-Catalyzed Tsuji-Trost Reactions Enabled by Aqueous Micellar Catalysis

Palladium-catalyzed allylic substitution, or "Tsuji-Trost"reactions, can be run under micellar catalysis conditions featuring not only chemistry in water but also numerous combinations of reaction partners that require low levels of palladium, typically on the order of 1000 ppm (0.1 mol %). These couplings are further characterized by especially mild conditions, leading to a number of cases not previously reported in an aqueous micellar medium. Inclusion of diverse nucleophiles, such as N-H heterocycles, alcohols, dicarbonyl compounds, and sulfonamides is described. Intramolecular cyclizations further illustrate the broad utility of this process. In addition to recycling studies, a multigram scale example is reported, indicative of the prospects for scale up.

In situ generated "lanthanum(iii) nitrate alkoxide" as a highly active and nearly neutral transesterification catalyst

In situ generated lanthanum(iii) nitrate alkoxide is a highly active and nearly neutral transesterification catalyst, which can promote non-epimerized transesterification of α-substituted chiral carboxylic esters under reflux conditions.