58434-29-0

Basic information

• Product Name: Hydroperoxide, (6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)methyl
• CAS NO: 58434-29-0
• Molecular Formula: C10H16O2
• Molecular Weight: 168.236
• Mol File: 58434-29-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Hydroperoxide, (6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)methyl(CAS DataBase Reference)
• NIST Chemistry Reference: Hydroperoxide, (6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)methyl(58434-29-0)
• EPA Substance Registry System: Hydroperoxide, (6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)methyl(58434-29-0)

Safety Data

• Hazardous Substances Data: 58434-29-0(Hazardous Substances Data)

Upstream product

• 22321-84-2 trans-pinocarveyl hydroperoxide 
• 177698-19-0 Beta-pinene 

Downstream Products

• 547-61-5 pinocarveol 
• 129222-74-8 6,6-Dimethyl-2-tritylperoxymethyl-bicyclo[3.1.1]hept-2-ene 
• 515-00-4 myrtenol 
• 16812-40-1 pinocarvone 
• 564-94-3 6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde 

Relevant articles and documents

Carbon-Carbon Bond Scission during the Reactions of Allylic Hydroperoxides with some Transition Metal Compounds. Result Relevant to a Recent Proposal

The proposal that 4-exo closure of an allylic peroxyl radical can account for the titled reactions of pinocarveyl hydroperoxide has been considered in the light of literature data, along with the results of reactions carried out with a range of alternative copper and iron reagents and with the previously examinated reagents in the presence or absence of suitable traps: an acid-catalysed pathway is proposed to account for the observed scission reaction.