58577-60-9

Basic information

• Product Name: 1,1,1-trichloro-4-phenyl-but-3-en-2-ol
• Synonyms: 1,1,1-trichloro-4-phenyl-but-3-en-2-ol
• CAS NO: 58577-60-9
• Molecular Weight: 251.54
• Mol File: 58577-60-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1,1,1-trichloro-4-phenyl-but-3-en-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1,1-trichloro-4-phenyl-but-3-en-2-ol(58577-60-9)
• EPA Substance Registry System: 1,1,1-trichloro-4-phenyl-but-3-en-2-ol(58577-60-9)

Safety Data

• Hazardous Substances Data: 58577-60-9(Hazardous Substances Data)

Upstream product

• 14371-10-9 (E)-3-phenylpropenal 
• 60-29-7 diethyl ether 
• 67-66-3 chloroform 
• 650-51-1 sodium trichloroacetate 
• 104-55-2 3-phenyl-propenal 
• 76-03-9 trichloroacetic acid 
• 56-23-5 tetrachloromethane 
• 5764-62-5 tributyl-trichloromethyl-stannane 

Downstream Products

• 78401-35-1 ((E)-3-Allyloxy-4,4,4-trichloro-but-1-enyl)-benzene 
• 98994-27-5 C₁₀H₇Cl₃O 
• 82772-46-1 ((Z)-4,4-Dichloro-3-methoxy-but-1-enyl)-benzene 
• 88981-42-4 Chloromethyl styryl ketone 
• 128573-54-6 4-phenyl-2-hydroxy-3,4-butenoic acid 
• 2051-95-8 succinylbenzene 
• 98994-27-5 1,1,1-trichloro-4-phenylbut-(E)-3-en-2-one 
• 78401-61-3 ((E)-3-Allyloxy-4,4-dichloro-buta-1,3-dienyl)-benzene 
• 78401-48-6 (E)-4,4-Dichloro-1-phenyl-hepta-1,6-dien-3-one 
• 118171-44-1 2,2,2-trichloro-1-styrylethyl acetate 

Relevant articles and documents

Organocatalyzed asymmetric vinylogous Michael addition of α,β-unsaturated γ-butyrolactam

Highly efficient asymmetric vinylogous 1,6-Michael addition of α,β-unsaturated γ-butyrolactam to 3-methyl-4-nitro-5-alkenyl- isoxazoles and Michael addition to trichloromethyl ketones by using a chiral quinine-derived squaramide organocatalyst were described, giving products with high diastereo- and enantioselectivities (up to >25:1 dr and 96% ee).

Decomposition of sodium trichloroacetate in the presence of quaternary ammonium under microwave irradiation: A convenient one-pot synthesis of α-hydroxy acids in water

A good yielding phase-transfer-catalyzed procedure for one-pot preparation of α-hydroxy acids from carbonyl compounds and sodium trichloroacetate by in situ addition and hydrolysis under microwave irradiation is described. Decomposition of sodium trichloroacetate is strongly accelerated by the presence of quaternary ammonium. The reaction can be conducted in water. Copyright Taylor & Francis Group, LLC.

NOVEL SELECTIVE SYNTHESIS OF α-CHLOROMETHYL, α,α-DICHLOROMETHYL, AND α,α,α-TRICHLOROMETHYL KETONES FROM ALDEHYDE UTILIZING ELECTROREDUCTION AS KEY REACTIONS

A variety of α-chloromethyl, α,α-dichloromethyl, and α,α,α-trichloromethyl ketones were synthesized from aldehyde utilizing cathodic reduction as key reactions.