58636-76-3Relevant articles and documents
Electrolytic Partial Fluorination of Organic Compounds. 14. The First Electrosynthesis of Hypervalent Iodobenzene Difluoride Derivatives and Its Application to Indirect Anodic gem-Difluorination
Fuchigami, Toshio,Fujita, Toshiyasu
, p. 7190 - 7192 (1994)
The electrosynthesis of hypervalent iodobenzene difluorides was accomplished by anodic oxidation of p-nitro- and p-methoxyiodobenzenes with Et3N*3HF in anhydrous acetonitrile, and p-methoxyiodobenzene difluoride was used as a mediator for indirect anodic
Deconstructing the Catalytic, Vicinal Difluorination of Alkenes: HF-Free Synthesis and Structural Study of p-TolIF2
Sarie, Jér?me C.,Thiehoff, Christian,Mudd, Richard J.,Daniliuc, Constantin G.,Kehr, Gerald,Gilmour, Ryan
, p. 11792 - 11798 (2017/11/24)
Recently, contemporaneous strategies to achieve the vicinal difluorination of alkenes via an I(I)/I(III) catalysis manifold were independently reported by this laboratory and by Jacobsen and co-workers. Both strategies proceed through a transient ArI(III)