58644-57-8Relevant articles and documents
METHOD OF CARBON MONOXIDE FIXATION AND METHOD OF AMINE FORMYLATION
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Paragraph 0078; 0081-0085; 0096-0098, (2021/02/19)
The present invention relates to a method for fixing carbon monoxide in a metal-free condition and a method for formating amine using the same.
Mn(II)-Catalyzed N -Acylation of Amines
Ma, Juan,Zhang, Jingyu,Gong, Hang
, p. 693 - 703 (2019/01/23)
A practical protocol has been developed here for the Mn(II)-catalyzed N -acylation of amines with high yields using N, N -dimethylformamide and other amides as the carbonyl source. The protocol is simple, does not require any acid, base, ligand, or other additives, and encompasses a broad substrate scope for primary, secondary, and heterocyclic amines.
Method for synthesizing formamide derivative through Mn-catalyzed formylation reaction
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Paragraph 0073; 0074, (2018/05/16)
The invention discloses a method for synthesizing a formamide derivative through Mn-catalyzed formylation reaction. The method disclosed by the invention is characterized in that an amine compound anda formamide compound are subjected to one-pot reaction under the catalytic action of manganese salt to generate the formamide derivative. The method disclosed by the invention has the beneficial effects that reaction raw materials and a catalyst are cheap and easy to get, reaction steps and operation are simple, the advantages of high reaction selectivity, high yield and expandable reaction are achieved, and the defects that a reagent is high in toxicity, the catalyst is expensive, reaction steps are tedious and byproducts are more in the prior art are overcome.