587-78-0 Usage
Type of compound
Salt
Constituents
Pyridinium cation and bromide anion
Structural feature
4-fluorophenylmethyl group attached to the pyridinium ring
Application
Organic synthesis and pharmaceutical research
Role
Chiral ligand in asymmetric catalysis
Potential medical applications
Treatment of neurological disorders and cancer
Versatility
Range of potential uses in chemical and biomedical research
Check Digit Verification of cas no
The CAS Registry Mumber 587-78-0 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 5,8 and 7 respectively; the second part has 2 digits, 7 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 587-78:
(5*5)+(4*8)+(3*7)+(2*7)+(1*8)=100
100 % 10 = 0
So 587-78-0 is a valid CAS Registry Number.
InChI:InChI=1/C12H11FN.BrH/c13-12-6-4-11(5-7-12)10-14-8-2-1-3-9-14;/h1-9H,10H2;1H/q+1;/p-1
587-78-0Relevant articles and documents
Coupling Photocatalysis and Substitution Chemistry to Expand and Normalize Redox-Active Halides
Rathnayake, Manjula D.,Weaver, Jimmie D.
supporting information, p. 2036 - 2041 (2021/04/05)
Photocatalysis can generate radicals in a controlled fashion and has become an important synthetic strategy. However, limitations due to the reducibility of alkyl halides prevent their broader implementation. Herein we explore the use of nucleophiles that can substitute the halide and serve as an electron capture motif that normalize the variable redox potentials across substrates. When used with photocatalysis, bench-stable, commercially available collidinium salts prove to be excellent radical precursors with a broad scope.