58775-63-6

Basic information

• Product Name: rac-4-allyl-3-methylcyclohex-2-enone
• Synonyms: rac-4-allyl-3-methylcyclohex-2-enone
• CAS NO: 58775-63-6
• Molecular Weight: 150.221
• Mol File: 58775-63-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: rac-4-allyl-3-methylcyclohex-2-enone(CAS DataBase Reference)
• NIST Chemistry Reference: rac-4-allyl-3-methylcyclohex-2-enone(58775-63-6)
• EPA Substance Registry System: rac-4-allyl-3-methylcyclohex-2-enone(58775-63-6)

Safety Data

• Hazardous Substances Data: 58775-63-6(Hazardous Substances Data)

Upstream product

• 23074-59-1 3-isobutoxycyclohex-2-en-1-one 
• 504-02-9 1,3-cylohexanedione 
• 58775-54-5 (+/-)-3-ethoxy-6-(prop-2-enyl)-cyclohex-2-en-1-one 
• 5323-87-5 3-Ethoxycyclohex-2-en-1-one 
• 16807-60-6 3-methoxycyclohex-2-en-1-one 
• 917-54-4 methyllithium 
• 106-95-6 allyl bromide 
• 40649-34-1 6-allyl-3-isobutoxycyclohex-2-en-1-one 

Downstream Products

• 1638678-11-1 4,6-diallyl-3-methylcyclohex-2-enone 
• 944276-11-3 4-allyl-3,3-dimethylcyclohexan-1-one 
• 1323443-37-3 rac-4-allyl-3,6-dimethylcyclohex-2-enone 
• 57904-79-7 3-(2-methyl-4-oxo-2-cyclohexenyl)propanol p-toluenesulfonate ethylene thioketal 
• 42723-36-4 3-(2-methyl-4-oxo-2-cyclohexenyl)propane-1-triphenylphosphonium iodide ethylene thioketal 
• 42723-49-9 7-methyl-13-(2-methyl-4-hydroxy-2-cyclohexenyl)-trans,trans-6,10-tridecadien-2-yne 
• 42722-77-0 dl-7-methyl-13-(2-methyl-4-oxo-2-cyclohexenyl)-trans,trans-6,10-tridecadien-2-yne 

Relevant articles and documents

A Unique Skeletal Rearrangement of a Bicyclo[33.1]nonanetrione to a Tetrahydroquinolin-2(1 H)-one System

The unexpected formation of a 4-hydroxytetrahydroquinolin-2(1 H)-one from a bicyclo[3.3.1]nonanetrione system and an amino alcohol in the presence of TsOH is reported. The mechanism of this transformation was studied by DFT calculations. The reaction provides an entry to the synthesis of highly functionalized 4-hydroxytetrahydroquinolin-2(1 H)-ones.

A total synthesis of sarcandralactone A: A general, concise, RCM enabled approach to lindenanolide sesquiterpenoids

A total synthesis of lindenane-type sesquiterpenoid natural product sarcandralactone A and its close sibling 5-epi-shizukanolide has been accomplished through a concise strategy in which a one-pot γ-lactone annulation and a RCM reaction constitute pivotal

Direct Formation of the Steroid Nucleus by a Biomimetic Cyclization

The aim of this study was to synthesize the trienynol 3 and to study its cyclization.The substrate was synthesized by a convergent route, the key step being the stereoselective Wittig-Schlosser condensation of the known aldehyde 19 with the phosphorane 18