58871-09-3

Basic information

• Product Name: 6-O-(TERT-BUTYLDIMETHYLSILYL)-D-GLUCAL
• Synonyms: 6-O-(TERT-BUTYLDIMETHYLSILYL)-D-GLUCAL
• CAS NO: 58871-09-3
• Molecular Formula: C₁₂H₂₄O₄Si
• Molecular Weight: 294.42
• Mol File: 58871-09-3.mol
• Article Data: 26

Chemical Properties

• Flash Point: >230 °F
• Appearance: /
• Density: 1.06 g/mL at 25 °C(lit.)
• Refractive Index: n20/D 1.485(lit.)
• CAS DataBase Reference: 6-O-(TERT-BUTYLDIMETHYLSILYL)-D-GLUCAL(CAS DataBase Reference)
• NIST Chemistry Reference: 6-O-(TERT-BUTYLDIMETHYLSILYL)-D-GLUCAL(58871-09-3)
• EPA Substance Registry System: 6-O-(TERT-BUTYLDIMETHYLSILYL)-D-GLUCAL(58871-09-3)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 58871-09-3(Hazardous Substances Data)

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 13265-84-4 D-glucal 
• 82112-21-8 N,O-bis(tertbutyldimethylsilyl)acetamide 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 2873-29-2 D-glucal triacetate 
• 3971-47-9 (3S,4R)-dihydroxy-(2R)-(hydroxymethyl)tetrahydropyran 

Downstream Products

• 13265-84-4 D-glucal 
• 136656-49-0 3,4-di-O-acetyl-1,5-anhydro-6-O-t-butyldimethylsilyl-2-deoxy-D-arabino-hex-1-enitol 
• 129840-37-5 1,5-anhydro-3,4-di-O-benzyl-6-O-(tert-butyldimethylsilyl)-2-deoxy-D-arabino-hex-1-enitol 
• 126461-69-6 1,5-anhydro-3-O-benzyl-6-O-tert-butyldimetylsilyl-2-deoxy-D-arabino-hex-1-enopyranose 
• 114861-44-8 Benzoic acid (2R,3S,4R)-2-(tert-butyl-dimethyl-silanyloxymethyl)-3-hydroxy-3,4-dihydro-2H-pyran-4-yl ester 
• 136573-59-6 1,5-anhydro-3,4-di-O-benzoyl-6-O-t-butyldimethylsilyl-2-deoxy-D-arabino-hex-1-enitol 
• 114861-44-8 (-)-(2R,3R,4R)-2-(((tert-butyldimethylsilyl)oxy)methyl)-3-hydroxy-4-(benzoyloxy)-3,4-dihydro-2H-pyran 
• 131156-54-2 (2R,3R,4R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-4-(tert-butyl-diphenyl-silanyloxy)-3,4-dihydro-2H-pyran-3-ol 
• 137792-62-2 4-O-benzyl-6-O-tert-butyldimethylsilyl-D-(-)-glucal 
• 859214-78-1 [3-(4-methoxy-phenoxy)-6-phenyl-3,6-dihydro-2H-pyran-2-yl]-methanol 
• 859215-04-6 O-[3-(4-methoxy-phenoxy)-6-phenyl-3,6-dihydro-2H-pyran-2-ylmethyl]-hydroxylamine 
• 859214-82-7 (6-phenylethynyl-3-p-tolyloxy-3,6-dihydro-2H-pyran-2-yl)-methanol 
• 859214-76-9 carbonic acid 2-(tert-butyl-dimethyl-silanyloxymethyl)-6-phenyl-3,6-dihydro-2H-pyran-3-yl ester ethyl ester 
• 859214-77-0 tert-butyl-[3-(4-methoxy-phenoxy)-6-phenyl-3,6-dihydro-2H-pyran-2-ylmethoxy]-dimethyl-silane 

Relevant articles and documents

MOLECULAR PROBES FOR ANALYSIS OF METABOLISM OF GLYCOLYSIS INHIBITORS PRODRUGS AND SYNTHESIS METHODS THEREFORE

The present invention relates to compounds according to structure (I) whereby one of R1 to R3 is -OCOCD3 and the other two are either hydroxyl or OAc, their synthesis and their use in for the analysis of the metabolism of glycolysis inhibitors.

NOVEL ACETATES OF 2-DEOXY MONOSACCHARIDES WITH ANTICANCER ACTIVITY

Novel compounds and methods of using the same to inhibit glycolysis and treat cancer and other diseases are provided herein.

Total synthesis of cryptopyranmoscatone B1 from 3,4,6-tri-O-acetyl-d-glucal

The first stereoselective total synthesis of the natural cryptopyranmoscatone B1 has been accomplished from 3,4,6-tri-O-acetyl-d-glucal. In addition to the double cross-metathesis reaction, a tandem nucleophilic addition-diastereoselective reduction of an