59034-18-3Relevant articles and documents
Versatile CuI/Pd0 dual catalysis for the synthesis of quaternary α-allylated carbonyl compounds: Development, mechanistic investigations and scope
Nahra, Fady,Mace, Yohan,Boreux, Arnaud,Billard, Francois,Riant, Olivier
supporting information, p. 10970 - 10981 (2014/09/17)
We report herein a versatile cooperative dual catalysis reaction based on a CuI/Pd0 system. Mechanistic investigation shows that every component plays a crucial role in determining the reaction outcome. The reaction is successfully extended to various substrates; such as α,β-unsaturated ketones, malonates and coumarins. The strategy tolerates different substitution patterns and affords good yields for each family of substrates.
Electrochemical Catalysis of a 5-Endo-Trig Cyclization in Bicontinuous Microemulsions
Gao, Jianxin,Rusling, James F.
, p. 218 - 219 (2007/10/03)
-
Carbocyclic Ring Expansion Reactions via Radical Chain Processes
Baldwin, Jack E.,Adlington, Robert M.,Robertson, Jeremy
, p. 1404 - 1406 (2007/10/02)
Free radical mediated ring expansion of cis- and trans-α-substituted-β-stannylcyclohexanones provides efficient routes to cis- and trans-cyclononenones and cyclodecenones; the cis-/trans-geometry of the precursor controls the alkene geometry of the ring-e