59052-82-3

Basic information

• Product Name: CYCLODODECYL FORMATE
• Synonyms: CYCLODODECYL FORMATE;Cyclododecanol,formate;Formic acid cyclododecyl ester;Cyclododecanol, 1-formate;Einecs 261-575-3
• CAS NO: 59052-82-3
• Molecular Formula: C₁₃H₂₄O₂
• Molecular Weight: 212.33
• EINECS: 261-575-3
• Mol File: 59052-82-3.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 295.9°C at 760 mmHg
• Flash Point: 120.2°C
• Appearance: /
• Density: 0.92g/cm³
• Vapor Pressure: 0.00148mmHg at 25°C
• Refractive Index: 1.456
• CAS DataBase Reference: CYCLODODECYL FORMATE(CAS DataBase Reference)
• NIST Chemistry Reference: CYCLODODECYL FORMATE(59052-82-3)
• EPA Substance Registry System: CYCLODODECYL FORMATE(59052-82-3)

Safety Data

• Hazardous Substances Data: 59052-82-3(Hazardous Substances Data)

Usage

General Description

Cyclododecyl formate is an organic compound with the chemical formula C13H26O2. It is a clear, colorless liquid with a fruity odor, commonly used as a solvent in various industrial applications. Cyclododecyl formate is also used as a flavoring agent in food products and as a fragrance in cosmetic and personal care products. It is considered to have low toxicity and is generally regarded as safe for use in these applications. This chemical is also used in the production of polymers, resins, and other specialty chemicals due to its solvency and compatibility with various materials. Overall, cyclododecyl formate is a versatile chemical with a range of uses in different industries, from food and fragrance to industrial processes.

InChI:InChI=1/C13H24O2/c14-12-15-13-10-8-6-4-2-1-3-5-7-9-11-13/h12-13H,1-11H2

Upstream product

• 1724-39-6 cyclododecanol 
• 75-87-6 chloral 
• 7795-35-9 cyclododecyl bromide 
• 68-12-2 N,N-dimethyl-formamide 
• 830-13-7 cyclododecanone 
• 109-94-4 formic acid ethyl ester 
• 64-18-6 formic acid 

Relevant articles and documents

Enabling the Use of Alkyl Thianthrenium Salts in Cross-Coupling Reactions by Copper Catalysis

Alkyl groups are one of the most widely used groups in organic synthesis. Here, a a series of thianthrenium salts have been synthesized that act as reliable alkylation reagents and readily engage in copper-catalyzed Sonogashira reactions to build C(sp3)?C(sp) bonds under mild photochemical conditions. Diverse alkyl thianthrenium salts, including methyl and disubstituted thianthrenium salts, are employed with great functional breadth, since sensitive Cl, Br, and I atoms, which are poorly tolerated in conventional approaches, are compatible. The generality of the developed alkyl reagents has also been demonstrated in copper-catalyzed Kumada reactions.

Tribromoisocyanuric acid (TBCA) as a mild and metal free catalyst for the acetylation and formylation of hydroxyl groups under solvent free conditions

A convenient approach for acetylation and formylation of various types of alcohols and phenols with acetic anhydride and formic acid in the presence of Tribromoisocyanuric acid (TBCA) as catalyst is reported. The reactions were carried out under solvent-free condition and in good to high yields at room temperature. This present method is featured with relatively mild reaction conditions, simple operation, broad substrate scope, clean work-up, short reaction times, good to high yields, excellent selectivity and also avoids tedious purifications and the use of toxic reagents.

Formylation of alcohol with formic acid under solvent-free and neutral conditions catalyzed by free I2 or I2 generated in situ from Fe(NO3)3·9H2O/NaI

Different alcohols were formylated by formic acid under solvent-free conditions in the presence of iodine as the catalyst with good-to-high yields at room temperature. I2 generated in situ from Fe(NO3) 3·9H2O/NaI also catalyzed the formylation of the alcohols under solvent-free conditions. This gives a green and efficient reaction at room temperature, in which the use of toxic and corrosive molecular I2 is avoided.