5910-14-5

Basic information

• Product Name: 2,2,3,3-Tetramethylaziridine
• Synonyms: 2,2,3,3-Tetramethylaziridine
• CAS NO: 5910-14-5
• Molecular Formula: C6H13N
• Molecular Weight: 99.1741
• Mol File: 5910-14-5.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 79.8°Cat760mmHg
• Flash Point: °C
• Appearance: /
• Density: 0.786g/cm³
• Vapor Pressure: 87.7mmHg at 25°C
• Refractive Index: 1.409
• PKA: 8.43±0.60(Predicted)
• CAS DataBase Reference: 2,2,3,3-Tetramethylaziridine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2,3,3-Tetramethylaziridine(5910-14-5)
• EPA Substance Registry System: 2,2,3,3-Tetramethylaziridine(5910-14-5)

Safety Data

• Hazardous Substances Data: 5910-14-5(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 82, p. 6068, 1960 DOI: 10.1021/ja01508a024

InChI:InChI=1/C6H13N/c1-5(2)6(3,4)7-5/h7H,1-4H3

Upstream product

• 563-79-1 2,3-Dimethyl-2-butene 
• 114777-96-7 2-azido-3-bromo-2,3-dimethylbutane 
• 887376-10-5 dimethyl 2,2,3,3-tetramethyl-7a-phenyl-1,2,3,7a-tetrahydroimidazo[1,2-b]isoxazole-6,7-dicarboxylate 

Downstream Products

• 105027-76-7 2-nitro-α-<(2,2,3,3-tetramethyl-1-aziridinyl)methyl>-1H-imidazole-1-ethanol 
• 129449-02-1 α-<<(2-chloro-1,2,2-trimethylpropyl)amino>methyl>-2-nitro-1H-imidazole-1-ethanol hydrochloride 
• 129449-03-2 α-<<(2-bromo-1,2,2-dimethylpropyl)amino>methyl>-2-nitro-1H-imidazole-1-ethanol hydrobromide 

Relevant articles and documents

Direct aziridination of alkenes by a cationic (Salen)ruthenium(VI) nitrido complex

[RuVI(N)(salchda)(CH3OH)]PF6 (1) (salchda = N,N′-bis(salicylidene)o-cyclohexyldiamine dianion) reacts readily with 2,3-dimethyl-2-butene at room temperature in the presence of pyridine or 1-methylimidazole to give initially [RuVI(Az1(-H))(salchda)(py)]PF6 (2, Az1 = 2,2,3,3-tetramethylaziridine), which is then slowly reduced to [RuIII(Az1)(salchda)(py)]PF6 (3). 1 also reacts with a variety of aryl-substituted alkenes such as styrene and trans-β-methylstyrene in the presence of py or 1-MeIm to give the corresponding ruthenium(III) aziridine complexes. The structures of 3 and [RuIII(Az2)(salchda)(1-MeIm)]PF6 (4, Az2 = trans-2-methyl-3-phenylaziridine) have been determined by X-ray crystallography. The Ru-N(aziridine) distances (2.1049, 2.097 A) are consistent with a neutral aziridine ligand. The C-C and C-N distances in the aziridine ligands are all indicative of single bonds. Copyright

CHIMIE DES RADIOPROTECTEURS : II. SYNTHESE DE NOUVEAUX ACIDES S-(AMINOETHYL-2) PHOSPHOROTHIOIQUES SUBSTITUES

A new method for the synthesis of biologically interesting substituted S(2-aminoethyl) phosphorothioic acids H2NCR1R2-CR3R4SPO3H2 is described.It employs the sequence : olefine R1R2C=CR3R4 - α-bromoazide N3R1R2C-CBrR3R4 - aziridine or α-bromamin