5927-93-5Relevant articles and documents
Diastereoselective Synthesis of Cyclic sp 3 -Enriched cis -β-Alkoxysulfonyl Chlorides
Sokolov, Andriy,Golovach, Sergey,Kozlinsky, Ihor,Dolia, Krystyna,Tolmachev, Andrey A.,Kuchkovska, Yuliya,Grygorenko, Oleksandr O.
supporting information, p. 848 - 858 (2019/02/10)
A three-step synthesis of β-alkoxy-substituted alicyclic sulfonyl chlorides from cyclic alkenes and alcohols is reported. The scope of the method was studied for a range of the substrates with various steric and electronic properties. The title compounds were obtained on a hundred-gram scale in up to 52% overall yield scale as single cis -diastereomers.
Alkoxybromination of olefins using ammonium bromide and oxone
Kumar, Macharla Arun,Naresh, Mameda,Rohitha, Chozhiyath Nappunni,Narender, Nama
supporting information, p. 3121 - 3129 (2014/01/06)
A mild, efficient, and highly regio- and stereoselective method for the methoxy and ethoxy bromination of olefins has been developed using NH 4Br as a bromine source and Oxone as an oxidant. Various kinds of olefins (aromatic, linear, and cyclic olefins) afforded the corresponding alkoxy brominated products in moderate to excellent yields. Taylor & Francis Group, LLC.
Theoretical and infrared studies on the conformational isomerism of trans-2-bromo-alkoxycyclohexanes
Silla, Josue M.,Duarte, Claudimar J.,Freitas, Matheus P.,Ramalho, Teodorico C.,Cormanich, Rodrigo A.,Santos, Francisco P.,Tormena, Claudio F.,Rittner, Roberto
experimental part, p. 359 - 362 (2011/11/29)
The infrared spectra of trans-2-bromo-alkoxycyclohexanes (alcoxy = OMe, OEt, OiPr and OtBu) were obtained for the neat liquid, and the C-Br stretching mode was quantitatively analyzed to give insight about the conformational isomeris
