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59358-70-2

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59358-70-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 59358-70-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,9,3,5 and 8 respectively; the second part has 2 digits, 7 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 59358-70:
(7*5)+(6*9)+(5*3)+(4*5)+(3*8)+(2*7)+(1*0)=162
162 % 10 = 2
So 59358-70-2 is a valid CAS Registry Number.

59358-70-2Relevant articles and documents

Phenylene-bridged bis(benzimidazolium) (BBIm2+): a dicationic organic photoredox catalyst

Kodama, Takuya,Kubo, Maiko,Shinji, Wataru,Ohkubo, Kei,Tobisu, Mamoru

, p. 12109 - 12117 (2020/11/27)

A dicationic photoredox catalyst composed of phenylene-bridged bis(benzimidazolium) (BBIm2+) was designed, synthesised and demonstrated to promote the photochemical decarboxylative hydroxylation and dimerisation of carboxylic acids. The catalytic activity of BBIm2+ was higher than that for a monocation analogue, suggesting that the dicationic nature of BBIm2+ plays a key role in these decarboxylative reactions. The rate constant for the decay of the triplet-triplet absorption of the excited BBIm2+ increased with increasing concentration of the carboxylate anion with a saturated dependence, suggesting that photoinduced electron transfer occurs within the ion pair complex composed of the triplet excited state of BBIm2+ and a carboxylate anion.

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