59361-35-2Relevant articles and documents
Gas-Phase Reactions of Hexachlorodisilane with Vinyl Chloride and Allyl Chloride
Chernyshev,Komalenkova,Kapitova,Bykovchenko,Khromykh,Bochkarev
, p. 1447 - 1450 (2007/10/03)
Gas-phase reactions of hexachlorodisilane with vinyl chloride and allyl chloride is studied. Dichlorosilylene generated from Si2Cl6 reacts with the above chloroalkenes mainly at the C-Cl bond to form alkenyltrichlorosilanes. The yields of vinyltrichlorosilane and allyltrichlorosilane are 45-63 and 49-81%, respectively. A mechanism of the reactions of Si2Cl6 with vinyl chloride and allyl chloride is proposed.