59376-62-4

Basic information

• Product Name: 1,4-Pentadien-3-one, 1-phenyl-5-(trimethylsilyl)-, (E,E)-
• CAS NO: 59376-62-4
• Molecular Formula: C14H18OSi
• Molecular Weight: 230.382
• Mol File: 59376-62-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,4-Pentadien-3-one, 1-phenyl-5-(trimethylsilyl)-, (E,E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-Pentadien-3-one, 1-phenyl-5-(trimethylsilyl)-, (E,E)-(59376-62-4)
• EPA Substance Registry System: 1,4-Pentadien-3-one, 1-phenyl-5-(trimethylsilyl)-, (E,E)-(59376-62-4)

Safety Data

• Hazardous Substances Data: 59376-62-4(Hazardous Substances Data)

Upstream product

• 18178-59-1 (E)-1,2-bis(trimethylsilyl)ethene 
• 102-92-1 Cinnamoyl chloride 
• 81256-03-3 (1E,4E)-5-phenyl-1-trimethylsilyl-1,4-pentadien-3-ol 
• 14371-10-9 (E)-3-phenylpropenal 
• 42201-74-1 <β-(Trimethylsilyl)vinyl>magnesium bromide 
• 41309-43-7 (2-bromovinyl)trimethylsilane 

Downstream Products

• 81255-96-1 4-phenyl-2-cyclopenten-1-one 

Relevant articles and documents

Silicon-Directed Nazarov Reactions II. Preparation and Cyclization of β-Silyl-substituted Divinyl Ketones

Two general methods for the preparation of β-silyl-substituted divinyl ketones have been developed starting from either α,β-unsaturated aldehydes or simple ketones.Anhydrous FeCl3 induces the cyclization to cyclopentenones under mild conditions and in good yields with predictable and complete control over the position of the double bond in the five-membered ring.The observed effects of substituents on rate can be explained by a rate-determining cationic electrocyclization.Silyl substitution has been shown to retard the reaction.