5942-76-7Relevant articles and documents
α-Trifluoromethyl α-ethoxy β-vinyl anions: Stereoselective route to hindered β-ethoxy allylic alcohols and crotonates
Bonnet-Delpon, Danièle,Bouvet, Denis,Ourévitch, Michèle,Rock, Michael H.
, p. 288 - 292 (2007/10/03)
α-Trifluoromethyl β-bromo enol ethers 3 can be stereoselectively obtained through a sequential bromination-dehydrobromination of enol ethers 1. Bromine-lithium exchange, followed by subsequent trapping with electrophiles gives access to new functionalized CF3-enol ethers.