59431-14-0 Usage
Description
METHYLTHIOMETHYL PHENYL SULFONE is an organic compound that serves as a versatile building block and starting reagent in various chemical reactions and synthesis processes.
Uses
Used in Pharmaceutical Industry:
METHYLTHIOMETHYL PHENYL SULFONE is used as a nucleophilic and electrophilic building block for the asymmetric synthesis of 6-N-benzoyl-5′-O-benzyl-2′-deoxyadenosine and its anomer, contributing to the development of potential therapeutic agents.
Used in Chemical Synthesis:
METHYLTHIOMETHYL PHENYL SULFONE is used as a starting reagent in the preparation of methylthio arylbutadiynes (Ar-C=C-C=C-SCH3), which are important intermediates in the synthesis of various organic compounds.
Used in the Synthesis of Multidentate Methylthio Arylethynes (MTA) Derivatives:
METHYLTHIOMETHYL PHENYL SULFONE is used as a key component in the synthesis of various multidentate MTA derivatives, which have potential applications in the development of new materials and chemical compounds.
Check Digit Verification of cas no
The CAS Registry Mumber 59431-14-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,9,4,3 and 1 respectively; the second part has 2 digits, 1 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 59431-14:
(7*5)+(6*9)+(5*4)+(4*3)+(3*1)+(2*1)+(1*4)=130
130 % 10 = 0
So 59431-14-0 is a valid CAS Registry Number.
InChI:InChI=1/C8H10O2S2/c1-11-7-12(9,10)8-5-3-2-4-6-8/h2-6H,7H2,1H3
59431-14-0Relevant articles and documents
New methodology for obtention of some α-methylsulfanyl sulfones, synthetic precursors of carbonyl compounds
Wladislaw,Marzorati,Di Vitta,Claro Jr.
, p. 3485 - 3490 (1996)
The reaction of some α-phenylsulfonyl carboxylic acids with NaH in DMSO and dimethyl disulfide leading to α-methylsulfanyl alkyl phenyl sulfones is described.
Donor substituted sulfonyl carbenes, 2: Organothio sulfonyl carbenes
Schank, Kurt,Abdel Wahab, Aboel-Magd A.,Buegler, Stephan,Eigen, Peter,Jager, Juergen,Jost, Klaus
, p. 3721 - 3742 (2007/10/02)
Organothio sulfonyl carbenes 3 have been generated via ylid thermolysis or via α-elimination starting from α-chloro α-organothio sulfones and their derivatives. They have been captured by suitable nucleophilic trapping reagents (diazomethane, enol ethers, and other). Their nucleophilic carbenoid precursors could be trapped by an electrophilic olefin (ketene dithioacetal S,S-dioxides as Michael acceptors). Stable carbene Z-dimers could be obtained under various conditions. Bromine catalyzed isomerization to E-isomers proved to be reversible.
