59436-13-4

Basic information

• Product Name: 2′-nitrostyrene methyl ether
• Synonyms: 2′-nitrostyrene methyl ether
• CAS NO: 59436-13-4
• Molecular Weight: 179.175
• Mol File: 59436-13-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2′-nitrostyrene methyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: 2′-nitrostyrene methyl ether(59436-13-4)
• EPA Substance Registry System: 2′-nitrostyrene methyl ether(59436-13-4)

Safety Data

• Hazardous Substances Data: 59436-13-4(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 75867-47-9 trimethyl((2-nitrophenyl)ethynyl)silane 
• 4009-98-7 (methoxymethyl)triphenylphosphonium chloride 
• 552-89-6 2-nitro-benzaldehyde 
• 20763-19-3 (methoxymethylene)triphenylphosphorane 

Downstream Products

• 816419-86-0 (2-[1,3]dithian-2-ylmethyl-phenyl)-carbamic acid tert-butyl ester 
• 31553-11-4 2-(2-Methoxyethyl)-aniline 
• 948-65-2 2-phenyl-indole 
• 55577-25-8 2-(4-methylphenyl)-1H-indole 
• 1211-35-4 2-(4-chlorophenyl)-1H-indole 
• 4212-33-3 2-(2-nitrophenyl)-1-phenylethanone 
• 58751-65-8 1-(4-methylphenyl)-2-(2-nitrophenyl)ethanone 
• 75842-51-2 1-(4-Chloro-phenyl)-2-(2-nitro-phenyl)-ethanone 

Relevant articles and documents

Palladium-catalyzed synthesis of α-aryl acetophenones from styryl ethers and aryl diazonium saltsviaregioselective Heck arylation at room temperature

Preparation of α-aryl acetophenones from styryl ethers and aryldiazonium salts is described. The reaction is catalyzed by palladium acetate at room temperature in the absence of ligand and base. The developed method is highly attractive in terms of reaction conditions, substrate scope, functional group tolerance and yields. Synthetic applications of the present method are demonstrated by preparing α-aryl indoles and 3-aryl isocoumarin from styryl ethers.

Microwave-assisted in situ deprotection and ω-methoxylation of TMS-protected aryl alkynes

Using microwave technology, rapid ω-methoxylation of aryl alkynes is possible.