59456-68-7Relevant articles and documents
Alkoxybromination of olefins using ammonium bromide and oxone
Kumar, Macharla Arun,Naresh, Mameda,Rohitha, Chozhiyath Nappunni,Narender, Nama
supporting information, p. 3121 - 3129 (2014/01/06)
A mild, efficient, and highly regio- and stereoselective method for the methoxy and ethoxy bromination of olefins has been developed using NH 4Br as a bromine source and Oxone as an oxidant. Various kinds of olefins (aromatic, linear, and cyclic olefins) afforded the corresponding alkoxy brominated products in moderate to excellent yields. Taylor & Francis Group, LLC.
SYNTHESIS OF VICINAL BROMO-FLUORO ORGANIC COMPOUNDS USING ELEMENTAL FLUORINE
Brand, Michael,Rozen, Shlomo
, p. 419 - 424 (2007/10/02)
The direct action of fluorine on bromine at -78 deg C produces BrF which, without any isolation or purification, adds readily across various double bounds providing there is some hydrogen donor in the reaction mixture.Only trans addition of the elements o
