59472-05-8Relevant articles and documents
Solvent-free one-pot reduction of imines generated in situ from aldehydes and aniline by tributyltin hydride on silica gel
Hiroi, Ryoichi,Miyoshi, Norikazu,Wada, Makoto
, p. 274 - 275 (2002)
Imines generated in situ from aldehydes and aniline can be reduced using tributyltin hydride on silica gel under solvent-free conditions to provide the corresponding amines in good yields.
Method for synthesizing N-alkyl arylamine
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Paragraph 0053-0055, (2018/03/24)
The invention discloses a method for synthesizing N-alkyl arylamine. The method comprises the steps of adding amine, alcohol, a metal iridium catalyst, alkali to a reaction vessel for reflux reaction,cooling to room temperature after reaction, spin-drying a solvent and then conducting separation on columns to obtain a target compound. According to the method for synthesizing the N-alkyl arylamine, a series of N-benzylaniline derivatives are prepared by using transition metal iridium as the catalyst, weak base is used, by-product is water, and a product has relatively good yield, and has certain applicable value.
Chiral organometallic compounds
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, (2008/06/13)
A chiral, organometallic compound which, at a molecular level, has no C2 symmetry and comprises a carbon to carbon bond joining a chiral carbon atom to a carbon atom of a cyclopentadiene ring that is non-symmetrically substituted. Examples of such compounds include compounds of formula (I): STR1 wherein X1 and X2 are, independently, groups which are removable during a chemical reaction; M is titanium, zirconium or hafnium; and R1-8,11 are as specified in the description.