595-90-4Relevant articles and documents
Kupchik, E. J.,Connolly, R. E.
, p. 4747 - 4748 (1961)
Schwedt, G.,Ruessel, H. A.
, p. 301 - 303 (1973)
Coates, G. E.,Tranah, M.
, (1967)
-
Gilman,Rosenberg
, p. 2063 (1959)
-
Schmitz-Dumont
, p. 289,294 (1941)
The photochemistry of aromatic compounds IV. Photochemical behaviour of hexaphenylditin
Wilputte-Steinert,Nasielski
, p. 113 - 118 (1970)
The irradiation of hexaphenylditin yields "hot" triphenyltin radicals whose decomposition into diphenyltin and phenyl radicals competes with recombination and disproportionation.
The structures of ring-expanded NHC supported copper(
Charman, Rex S. C.,Liptrot, David J.,Lowe, John P.,Mahon, Mary F.
supporting information, p. 831 - 835 (2022/02/01)
Three ring-expanded N-heterocyclic carbene-supported copper(i) triphenylstannyls have been synthesised by the reaction of (RE-NHC)CuOtBu with triphenylstannane (RE-NHC = 6-Mes, 6-Dipp, 7-Dipp). The compounds were characterised by NMR spectroscopy and X-ray crystallography. Reaction of (6-Mes)CuSnPh3 with di-p-tolyl carbodiimide, phenyl isocyanate and phenylisothiocyanate gives access to a copper(i) benzamidinate, benzamide and benzothiamide respectively via phenyl transfer from the triphenylstannyl anion with concomitant formation of (Ph2Sn)n. Attempts to exploit this reactivity under a catalytic regime were hindered by rapid copper(i)-catalysed dismutation of Ph3SnH to Ph4Sn, various perphenylated tin oligomers, H2 and a metallic material thought to be Sn(0). Mechanistic insight was provided by reaction monitoring via NMR spectroscopy and mass spectrometry.
Continuous organomagnesium synthesis of organometallic compounds
Storozhenko,Grachev,Klochkov,Shiryaev
, p. 387 - 393 (2013/06/27)
Continuous organomagnesium synthesis of a number of organic derivatives of 14th group elements of the periodic table was examined in a column apparatus with an agitator. An effect of a molar ratio of reactants, temperature in a reaction zone, and other factors was studied on the yield and composition of the products.
