59555-69-0

Basic information

• Product Name: Benzene, [(4-methyl-3-pentenyl)sulfonyl]-
• CAS NO: 59555-69-0
• Molecular Formula: C12H16O2S
• Molecular Weight: 224.324
• Mol File: 59555-69-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, [(4-methyl-3-pentenyl)sulfonyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(4-methyl-3-pentenyl)sulfonyl]-(59555-69-0)
• EPA Substance Registry System: Benzene, [(4-methyl-3-pentenyl)sulfonyl]-(59555-69-0)

Safety Data

• Hazardous Substances Data: 59555-69-0(Hazardous Substances Data)

Upstream product

• 763-89-3 4-methylpent-3-en-1-ol 
• 873-55-2 sodium benzenesulfonate 
• 2270-59-9 1-bromo-4-methylpent-3-ene 
• 3112-85-4 methylphenylsulfonate 
• 870-63-3 prenyl bromide 

Downstream Products

• 116893-76-6 5-Benzenesulfonyl-2-methyl-dodec-2-en-6-ol 
• 1332861-91-2 C₂₂H₃₂O₄S 
• 1332861-92-3 (E)-3,8-dimethyl-5-(phenylsulfonyl)nona-2,7-dien-1-ol 
• 1235454-10-0 ((2-(4,4-dimethyl-2-phenylcyclobut-2-en-1-yl)ethyl)sulfonyl)benzene 
• 80989-87-3 2,2-dimethyl-1-(phenylsulfonyl)bicyclo<1.1.0>butane 
• 81583-18-8 trans-1-(1-hydroxy-1-methylethyl)-2-(phenylsulfonyl)cyclopropane 
• 59555-78-1 trans-1-(1,2-epoxy-1-methylethyl)-2-(phenylsulfonyl)cyclopropane 
• 81583-24-6 trans-1-(1-methylvinyl)-2-(phenylsulfonyl)cyclopropane 
• 59555-89-4 2-endo-(hydroxymethyl)-2-exo-methyl-1-(phenylsulfonyl)bicyclo<1.1.0>butane 
• 116893-89-1 Acetic acid (E)-6-benzenesulfonyl-9-methyl-deca-5,8-dienyl ester 
• 116893-89-1 Acetic acid (Z)-6-benzenesulfonyl-9-methyl-deca-5,8-dienyl ester 
• 116893-87-9 Acetic acid 2-benzenesulfonyl-5-methyl-1-(4-trityloxy-butyl)-hex-4-enyl ester 
• 116893-83-5 6-Benzenesulfonyl-9-methyl-1-trityloxy-dec-8-en-5-ol 
• 116893-91-5 C₃₆H₃₈O₃S 

Relevant articles and documents

Base-Mediated Radical Borylation of Alkyl Sulfones

A practical and direct method was developed for the production of versatile alkyl boronate esters via transition metal-free borylation of primary and secondary alkyl sulfones. The key to the success of the strategy is the use of bis(neopentyl glycolato) diboron (B2neop2), with a stoichiometric amount of base as a promoter. The practicality and industrial potential of this protocol are highlighted by its wide functional group tolerance, the late-stage modification of complex compounds, no need for further transesterification, and operational simplicity. Radical clock, radical trap experiments, and EPR studies were conducted which show that the borylation process involves radical intermediates.

IODINE-INDUCED IMINOTHIOLACTONIZATION OF γ,δ-UNSATURATED SECONDARY THIOAMIDES, NEW ENTRY TO 2-ACETOAMIDOTHIOPHENES

Iodine-induced cyclization of γ,δ-unsaturated secondary thioamides 1 proceeded regio- (5-exo-trigonal) and chemo- (sulfur-carbon bond formation)selectively, providing iminothiolactones 2, which were converted in two-step sequences (dehydroiodination and N-acetylation) into 2-acetoamidothiophenes 4.This procedure was performed in one flask to afford polysubstituted 2-aminothiophenes.