59671-42-0Relevant articles and documents
The search for the gas-phase negative ion pinacol rearrangement
Dua, Suresh K.,Whait, Robert B.,Alexander, Margaret J.,Hayes, Roger N.,Lebedev, Albert T.,Eichinger, Peter C. H.,Bowie, John H.
, p. 5709 - 5715 (1993)
Deprotonated 1,2-diols and β-methoxyhydrins often eliminate ROH (R = H, Me) on collisional activation in the gas phase. These losses do not involve a negative ion pinacol rearrangement in acyclic systems in which there are no conformational restraints on