5994-95-6

Basic information

• Product Name: Hydrazine, 1,2-diphenyl-1,2-bis(trimethylsilyl)-
• CAS NO: 5994-95-6
• Molecular Formula: C18H28N2Si2
• Molecular Weight: 328.605
• Mol File: 5994-95-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Hydrazine, 1,2-diphenyl-1,2-bis(trimethylsilyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Hydrazine, 1,2-diphenyl-1,2-bis(trimethylsilyl)-(5994-95-6)
• EPA Substance Registry System: Hydrazine, 1,2-diphenyl-1,2-bis(trimethylsilyl)-(5994-95-6)

Safety Data

• Hazardous Substances Data: 5994-95-6(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 1227476-15-4 Azobenzene 
• 122-66-7 diphenyl hydrazine 
• 4656-04-6 bis(trimethylsilyl)mercury 

Downstream Products

• 4147-89-1 1,1,1-trimethyl-N-phenyl-N-(trimethylsilyl)-silanamine 

Relevant articles and documents

Chemoselective deprotonative lithiation of azobenzenes: Reactions and mechanisms

Whereas standard strong bases (n-BuLi, s-BuLi/TMEDA, n-BuLi/t-BuOK, TMPMgCl·LiCl, and LDA) reduce the N=N bond of the parent azobenzene (Y = H), aromatic H→Li permutation occurs with LTMP when a suitable director of lithiation (Y = OMe, CONEt2, F) is present in the benzene residue of the azo compound. The method allows direct access to new substituted azobenzenes.

Novel Syntheses of Bis(trialkylsilyl)amines by Reductive Trialkylsilylation of Azo Compounds

Reduction of azo compounds with a system of a trialkylchlorosilane and lithium has been found to afford bis(trialkylsilyl)amines in the presence of a transition metal halide as a catalyst in THF.The reaction course was significantly modified by using t-butyldimethylchlorosilane as a trialkylchlorosilane.