600-40-8Relevant articles and documents
Bicentral oxidation of nitrosolic acids: Synthesis of 1,1-dinitroalkanes
Sheremetev, Aleksei B.,Aleksandrova, Natal'Ya S.,Suponitsky, Kyrill Yu.
, p. 215 - 217 (2010)
gem-Dinitrozo compounds are cleanly oxidized into the gem-dinitro analogues on treatment with formic acid/hydrogen peroxide system.
Reaction of nitrosolic acid salts with dinitrogen tetraoxide
Sheremetev,Aleksandrova,Tukhbatshin,Penzin,Belyakov
scheme or table, p. 487 - 488 (2010/07/09)
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Electrooxidative coupling of salts of nitro compounds with halide, nitrite, cyanide, and phenylsulfinate anions
Ilovaisky,Merkulova,Ogibin,Nikishin
, p. 1585 - 1592 (2007/10/03)
Electrolysis of salts of primary and secondary nitro compounds (nitroethane, 1- and 2-nitropropanes, nitrocyclohexane, and nitrocycloheptane) in the presence of excess halide, nitrite, cyanide, and phenylsulfinate anions under undivided and divided amperostatic electrolysis conditions in a two-phase medium (CH2Cl2/H2O) produces geminal nitrohalides (35-85% yields), dinitro compounds (15-51%), nitronitriles (6-27%), and nitrosulfones (50-70%). The salts of secondary nitro compounds form the products of oxidative coupling with halide and phenylsulfinate anions under the undivided electrolysis conditions. In all other cases, divided electrolysis is required.