6000-10-8

Basic information

• Product Name: Benzene, 1,1'-(1,2-cyclopropanediyl)bis[4-methoxy-, trans-
• CAS NO: 6000-10-8
• Molecular Formula: C17H18O2
• Molecular Weight: 254.329
• Mol File: 6000-10-8.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(1,2-cyclopropanediyl)bis[4-methoxy-, trans-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(1,2-cyclopropanediyl)bis[4-methoxy-, trans-(6000-10-8)
• EPA Substance Registry System: Benzene, 1,1'-(1,2-cyclopropanediyl)bis[4-methoxy-, trans-(6000-10-8)

Safety Data

• Hazardous Substances Data: 6000-10-8(Hazardous Substances Data)

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 637-69-4 4-Methoxystyrene 
• 29304-87-8 7-(4-methoxyphenyl)cyclohepta-1,3,5-triene 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 1433968-06-9 1-mesityl-2-((4-methoxybenzyl)thio)-1H-imidazole 
• 1433968-01-4 1-mesityl-2-((4-methoxybenzyl)sulfonyl)-3-methyl-1H-imidazolium trifluoromethanesulfonate 
• 1433968-04-7 C₄₈H₆₀AuN₄O₃S⁽¹⁺⁾*CF₃O₃S^(1-) 
• 824-94-2 p-methoxybenzyl chloride 
• 2373-89-9 4,4'-dimethoxychalcone 
• 4705-34-4 1,2-bis(4-methoxyphenyl)ethene 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 1692-39-3 (1R,2S)-1,2-bis(4-methoxyphenyl)cyclopropane 

Downstream Products

• 109423-43-0 C₃₃H₂₆N₂O₂ 
• 109423-43-0 C₃₃H₂₆N₂O₂ 
• 52751-67-4 3,5-bis-(4-methoxyphenyl) isoxazole 
• 20821-99-2 3,5-Bis(p-methoxyphenyl)-4,5-dihydroisoxazole 
• 96908-14-4 4-nitro-3,5-di(p-methoxyphenyl)isoxazole 
• 53629-01-9 erythro-1,2-Bis(p-methoxyphenyl)-1-propanol 
• 53629-01-9 threo-1,2-Bis(p-methoxyphenyl)-1-propanol 
• 76494-78-5 erythro-1,2-Bis(p-methoxyphenyl)-1-methoxypropane 
• 76494-78-5 threo-1,2-Bis(p-methoxyphenyl)-1-methoxypropane 
• 86396-68-1 cis-3,5-bis(4-methoxyphenyl)-1,2-dioxolane 
• 76494-72-9 erythro-1,2-Bis(p-methoxyphenyl)-1-acetoxypropane 
• 76494-72-9 threo-1,2-Bis(p-methoxyphenyl)-1-acetoxypropane 
• 34414-53-4 1,3-bis(4-methoxyphenyl)prop-1-ene 
• 123-11-5 4-methoxy-benzaldehyde 

Relevant articles and documents

cis-trans Isomerization of 1,2-Bis(4-metoxyphenyl)cyclopropanes via a Cationic Chain Mechanism

Radiation-induced cis-trans isomerization of 1,2-bis(4-metoxyphenyl)cyclopropanes(CP) has been investigated in benzonitrile solution.The isomerization from cis-CP to trans-CP proceeded efficiently ( G = 80 ) via a cationic chain mechanism.Three types of t

Cyclopropanation with gold(I) carbenes by retro-Buchner reaction from cycloheptatrienes

Cationic gold(I) promotes the retro-Buchner reaction of 7-substituted 1,3,5-cycloheptatrienes, leading to gold(I) carbenes that cyclopropanate alkenes.

Generation of Polyphenylene Radical Cations and Their Cosensitization Ability in the 9,10-Dicyanoanthracene-Sensitized Photochemical Chain Reactions of 1,2-Bis(4-methoxyphenyl)cyclopropane

Cosensitization effects of polyphenylene compounds (PP) such as biphenyl (BP), terphenyls (o-, m-, p-TP), and phenanthrene (Phen) in photoinduced electron-transfer reactions were examined. The 9,10-dicyanoanthracene (DCA)-sensitized cis-trans photoisomerization of 1,2-bis(4-methoxyphenyl)-cyclopropane (CP), which proceeds in a chain reaction via free radical cation of CP (CP.+) as a chain carrier, was accelerated by adding PP, particularly by TP. A similar accelerating effect was observed in the DCA-sensitized photooxygenation of CP as another example. BP and TP were more stable under the oxygenation condition than phenanthrene and naphthalene, which also accelerate the photooxygenation CP. CP.+ is generated by the direct electron transfer from CP to the excited singlet state of DCA (1DCA*) and also by the secondary electron transfer from CP to PP.+, which is generated by the primary electron transfer from PP to 1DCA*. The laser flash photolysis study revealed that the quantum yield for the formation of free CP.+ in the direct electron transfer from CP to 1DCA* (ΦCP.+ ≈ 0.1) was smaller than that in the presence of PP. This is due to the high yield of free PP.+ generation by the primary electron transfer and the efficient secondary electron transfer from CP to PP.+. The secondary electron transfers were found to take place in nearly diffusion-controlled rates (0.9-1.5 × 1010 M-1 s-1). The high yield of PP.+ as free radical ions does not seem to be the sole factor of the cosensitization of PP for the DCA-sensitized photoreactions of CP. The ratio of the quantum yields of the photoreactions to that of the initial CP.+ formation (turnover) also increased by the addition of PP from 3 (isomerization) and 15 (oxygenation) to 32-90 for both reactions. The second-order rate constant for the decay of CP.+ in aerated acetonitrile was decreased by a factor of 0.5-0.8 by the addition of PP. We concluded that the cosensitization effect in the photoreaction involves a π-complex formation between CP.+ and PP assisting the chain reaction as well as initial CP.+ formation.