60068-19-1

Basic information

• Product Name: Silane, [[1-(4-methoxyphenyl)cyclopropyl]oxy]trimethyl-
• CAS NO: 60068-19-1
• Molecular Formula: C13H20O2Si
• Molecular Weight: 236.386
• Mol File: 60068-19-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Silane, [[1-(4-methoxyphenyl)cyclopropyl]oxy]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [[1-(4-methoxyphenyl)cyclopropyl]oxy]trimethyl-(60068-19-1)
• EPA Substance Registry System: Silane, [[1-(4-methoxyphenyl)cyclopropyl]oxy]trimethyl-(60068-19-1)

Safety Data

• Hazardous Substances Data: 60068-19-1(Hazardous Substances Data)

Upstream product

• 55991-65-6 [1-(4-methoxyphenyl)vinyloxy]trimethylsilane 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 75-77-4 chloro-trimethyl-silane 
• 15973-65-6 1-(4-methoxyphenyl)cyclopropan-1-ol 
• 75-11-6 diiodomethane 

Downstream Products

• 65374-27-8 1-(p-Anisyl)-1-ethoxycyclopropan 
• 65374-26-7 1-Methoxy-1-(4-methoxyphenyl)cyclopropan 
• 127931-50-4 (4-methoxyphenyl)-4-(2-methylphenyl)butane-1,4-dione 
• 127931-51-5 1-Furan-2-yl-4-m-tolyl-butane-1,4-dione 
• 67756-16-5 1-(4'-chlorophenyl)-4-(4''-methoxyphenyl)-butane-1,4-dione 
• 113777-23-4 3-(1'-naphthyl)-1-(4''-methoxyphenyl)propan-1-one 
• 5739-38-8 1-(4-methoxyphenyl)-3-phenylpropan-1-one 
• 133559-46-3 1-(2-Fluorophenyl)-4-(4-methoxyphenyl)butane-1,4-dione 
• 136384-97-9 (Z)-2-Methyl-but-2-enedioic acid 1-[1-(4-methoxy-phenyl)-cyclopropyl] ester 4-methyl ester 
• 127931-49-1 1-(4-Methoxyphenyl)-4-(1-naphthyl)butane-1,4-dione 
• 133559-45-2 1-(3-Methoxyphenyl)-4-(4-methoxyphenyl)butane-1,4-dione 
• 60755-22-8 1-(4-methoxyphenyl)-4-phenyl-1,4-butanedione 
• 133559-47-4 1-(2-Pyridyl)-4-(4-methoxyphenyl)butane-1,4-dione 
• 15973-65-6 1-(4-methoxyphenyl)cyclopropan-1-ol 

Relevant articles and documents

Iron-Catalyzed Ring-Opening Reactions of Cyclopropanols with Alkenes and TBHP: Synthesis of 5-Oxo Peroxides

The ring opening of cyclopropanols is rarely used in multicomponent reactions. Herein we report the three-component reaction of cyclopropanols with alkenes and tert-butyl hydroperoxide (TBHP) catalyzed by an iron catalyst. This protocol enables the incorporation of both the β-carbonyl fragment and a peroxy unit across the C=C double bond regioselectively, thus allowing an efficient, facile access to 5-oxo peroxides. Modification of the biologically active molecules and various downstream derivatizations of the peroxides are also demonstrated.

Visible-Light-Induced Alkoxyl Radical Generation Enables Selective C(sp3)-C(sp3) Bond Cleavage and Functionalizations

The alkoxyl radical is an important reactive intermediate in mechanistic studies and organic synthesis; however, its current generation from alcohol oxidation heavily relies on transition metal activation under strong oxidative conditions. Here we report the first visible-light-induced alcohol oxidation to generate alkoxyl radicals by cyclic iodine(III) reagent catalysis under mild reaction conditions. The β-fragmentation of alkoxyl radicals enables selective C(sp3)-C(sp3) bond cleavage and alkynylation/alkenylation reactions with various strained cycloalkanols, and for the first time with linear alcohols.

A facile cyclopropanol synthesis from β-halo ester with Grignard reagent-samarium(II) diiodide couple

Transformation of α,β-halo ester to the cyclopropanols by a coupled reagent of samarium(II) diiodide with Grignard reagent in tetrahydrofuran-hexamethylphosphoric triamide was very successful under mild conditions.