60111-69-5

Basic information

• Product Name: BIS[BIS(TRIMETHYLSILYL)METHYL]-GERMANIUM II
• Synonyms: BIS[BIS(TRIMETHYLSILYL)METHYL]-GERMANIUM II;BIS[BIS(TRIMETHYLSILYLMETHYL)]GERMANIUM ll
• CAS NO: 60111-69-5
• Molecular Formula: C₁₄H₃₈GeSi₄
• Molecular Weight: 391.43
• Mol File: 60111-69-5.mol
• Article Data: 2

Chemical Properties

• Melting Point: 179-180°C
• Boiling Point: 110°C/0.001mmHg
• Appearance: /
• CAS DataBase Reference: BIS[BIS(TRIMETHYLSILYL)METHYL]-GERMANIUM II(CAS DataBase Reference)
• NIST Chemistry Reference: BIS[BIS(TRIMETHYLSILYL)METHYL]-GERMANIUM II(60111-69-5)
• EPA Substance Registry System: BIS[BIS(TRIMETHYLSILYL)METHYL]-GERMANIUM II(60111-69-5)

Safety Data

• TSCA: No
• Hazardous Substances Data: 60111-69-5(Hazardous Substances Data)

Usage

Description

BIS[BIS(TRIMETHYLSILYL)METHYL]-GERMANIUM II is a chemical compound characterized by the molecular formula C10H30GeSi6. It is a germanium-based derivative featuring two trimethylsilylmethyl groups, which contribute to its unique properties and applications in various fields.

Uses

Used in Organic Synthesis:
BIS[BIS(TRIMETHYLSILYL)METHYL]-GERMANIUM II is employed as a reagent for the introduction of trimethylsilylmethyl groups to a variety of organic substrates. Its ability to facilitate such modifications makes it a valuable asset in the synthesis of complex organic molecules.
Used in Semiconductor Industry:
In the realm of semiconductors, BIS[BIS(TRIMETHYLSILYL)METHYL]-GERMANIUM II is utilized for the production of germanium-based materials. These materials exhibit distinctive electronic and optical properties, which are beneficial for the development of advanced semiconductor devices and technologies.
Used in Chemical and Material Science Applications:
Due to its stability and compatibility with a broad spectrum of solvents and reaction conditions, BIS[BIS(TRIMETHYLSILYL)METHYL]-GERMANIUM II serves as a versatile tool in chemical and material science research and development. Its adaptability allows for its use in numerous experimental setups and processes.

InChI:InChI=1/C14H40GeSi4/c1-16(2,3)13(17(4,5)6)15-14(18(7,8)9)19(10,11)12/h13-14H,15H2,1-12H3

Upstream product

• 62487-23-4 bis[bis(trimethylsilyl)methyl]germanium(II) dimer 
• 401587-52-8 (C₆H₅C(C₆H₅)O)Ge(CH(Si(CH₃)3)2)2 

Downstream Products

• 586418-36-2 (((CH₃)3Si)2CH)2GeIC₄H₉ 
• 586418-37-3 (((CH₃)3Si)2CH)2GeIC₄H₉ 
• 71-43-2 benzene 
• 586418-35-1 [(Me₃Si)2CH]2GeI(Ph) 
• 586418-33-9 (((CH₃)3Si)2CH)2GeIC₅H₉ 
• 401587-63-1 C₆H₅CNHGe(CH(Si(CH₃)3)2)2C₆H₅ 
• 401587-59-5 ClC₆H₄COGe(CH(Si(CH₃)3)2)2C₆H₄Cl 
• 586418-25-9 (((CH₃)3Si)2CH)2GeI(C₄H₇O) 
• 586418-32-8 (((CH₃)3Si)2CH)2GeI(C₄H₇O₂) 
• 586418-31-7 (((CH₃)3Si)2CH)2GeI(C₂H₅OCHCH₃) 
• 401587-61-9 CH₃C₆H₄COGe(CH(Si(CH₃)3)2)2C₆H₄CH₃ 
• 156298-12-3 C₄H₂GeN(O)2(C₆H₅)(CH(Si(CH₃)3)2)2 
• 153970-04-8 (C₆H₂(CH₃)3)2Si(N₃)NGe(CH(Si(CH₃)3)2)2 
• 156783-37-8 (C₆H₅)2SiN(GeN₃(CH(Si(CH₃)3)2)2)N₃Si(C₆H₅)2NHGe(OH)(CH(Si(CH₃)3)2)2 

Relevant articles and documents

Subvalent Group 4B Metal Alkyls and Amides. Part 8. Germanium and Tin Carbene Analogues MR2 : Syntheses and Structures in the Gas Phase (Electron Diffraction); Molecular-orbital Calculations for MH2 and GeMe2

Bisgermanium, GeR2 , is conveniently prepared from GeCl2(diox) (diox = 1,4-dioxane) (for which an improved synthesis, from GeCl4 and SnHBun3, is reported) and 2MgCl(R)(OEt2), MgR2(diox)0.5, or MgR2(OEt