60127-34-6

Basic information

• Product Name: 4-methoxyphenyl 4-methoxybenzoate
• Synonyms: 4-methoxyphenyl 4-methoxybenzoate
• CAS NO: 60127-34-6
• Molecular Formula: C₁₅H₁₄O₄
• Molecular Weight: 258.26926
• Mol File: 60127-34-6.mol
• Article Data: 25

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-methoxyphenyl 4-methoxybenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methoxyphenyl 4-methoxybenzoate(60127-34-6)
• EPA Substance Registry System: 4-methoxyphenyl 4-methoxybenzoate(60127-34-6)

Safety Data

• Hazardous Substances Data: 60127-34-6(Hazardous Substances Data)

Upstream product

• 100-07-2 4-methoxy-benzoyl chloride 
• 150-76-5 4-methoxy-phenol 
• 849-83-2 bis(4-methoxybenzoyl) peroxide 
• 10019-24-6 1,1,2,2-tetrakis(4-methoxyphenyl)ethene 
• 100-09-4 4-methoxybenzoic acid 
• 116883-43-3 O,O′-bis(4-methoxyphenyl) thiocarbonate 
• 5720-07-0 4-methoxyphenylboronic acid 
• 455-32-3 benzoyl fluoride 
• 53271-44-6 S-(4-methylphenyl) thio(4-methoxybenzoate) 
• 701-53-1 p-methoxybenzoyl fluoride 
• 201230-82-2 carbon monoxide 
• 123-11-5 4-methoxy-benzaldehyde 
• 104-93-8 p-methylanizole 
• 155164-68-4 4,5-Dichloro-2-(4-methoxy-benzoyl)-2H-pyridazin-3-one 

Downstream Products

• 16762-04-2 2-hydroxy-4',5-dimethoxybenzophenone 
• 80427-30-1 4-Methoxy-benzoic acid 4-methoxy-3-(4-methoxy-benzoyl)-phenyl ester 
• 80427-36-7 (5-Hydroxy-2-methoxy-phenyl)-(4-methoxy-phenyl)-methanone 

Relevant articles and documents

Decarboxylative Hydroxylation of Benzoic Acids

Herein, we report the first decarboxylative hydroxylation to synthesize phenols from benzoic acids at 35 °C via photoinduced ligand-to-metal charge transfer (LMCT)-enabled radical decarboxylative carbometalation. The aromatic decarboxylative hydroxylation is synthetically promising due to its mild conditions, broad substrate scope, and late-stage applications.

Rhodium-catalyzed synthesis of esters from aryl iodides and alcohols: use of alcohols with/without the assistance of aldehydes as carbon monoxide and nucleophile sources

A CO-gas-free rhodium-catalyzed alkoxycarbonylation of aryl iodide with alcohols has been developed. Alcohols, with/without the aid of an aldehyde, were used as a carbon monoxide and nucleophile source. The former synthesis afforded better yields of the alkoxycarbonylated products. Moreover, phenols also afforded phenoxycarbonylation products with high yields.

K2CO3-promoted formation of aryl esters from primary aryl amides by the acyl-acyl exchange process

A new acyl-acyl exchange reaction has been developed for the formation of aryl esters from primary aryl amides. The reaction could occur under mild reaction conditions with catalytic quantities of K2CO3, and could afford moderate to good yields of the desired products.