60216-44-6

Basic information

• Product Name: (E)-1-(Trimethylsilyl)-3-hexen-1-yne
• Synonyms: (E)-1-(Trimethylsilyl)-3-hexen-1-yne
• CAS NO: 60216-44-6
• Molecular Formula: C9H16Si
• Molecular Weight: 152.31
• Mol File: 60216-44-6.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (E)-1-(Trimethylsilyl)-3-hexen-1-yne(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-(Trimethylsilyl)-3-hexen-1-yne(60216-44-6)
• EPA Substance Registry System: (E)-1-(Trimethylsilyl)-3-hexen-1-yne(60216-44-6)

Safety Data

• Hazardous Substances Data: 60216-44-6(Hazardous Substances Data)

Upstream product

• 31849-78-2 (Z)-1-bromo-1-butene 
• 1066-54-2 trimethylsilylacetylene 
• 123-38-6 propionaldehyde 
• 177343-11-2 1,1-bis(trimethylsilyl)-2-propyne 
• 31844-98-1 (E)/(Z)-1-bromo-1-butene 

Relevant articles and documents

Regioselective synthesis of natural and unnatural (Z)-3-(1- alkylidene)phthalides and 3-substituted isocoumarins starting from methyl 2- hydroxybenzoates

(Z)-3-(1-Alkylidene)phthalides and 3-substituted isocoumarins, which include compounds bearing a substituent on their benzene ring, have been selectively and efficiently synthesized by a new protocol which involves: (i) the conversion of methyl 2-hydroxybenzoates into the corresponding nonaflates; (ii) Pd-catalyzed alkynylation reactions of these derivatives; (iii) the conversion of the so obtained methyl 2-(1-alkynyl)benzoates into the corresponding carboxylic acids followed by a transition metal-catalyzed heteroannulation reaction. This procedure has been used to prepare either natural products such as senkyunolide B, senkyunolide C, 3-propylisocoumarin and artemidin, or the MEM-ether of senkyunolide E. The regioselectivity of the transition metal-catalyzed cyclization reactions of 2-(1-alkynyl)benzoic acids has proven to be affected either by the catalyst used or the type of 1- alkynyl group present in these carboxylic acids. (C) 2000 Elsevier Science Ltd.

Sila-pheromones: Silicon analogues of the female sex pheromone of the processionary moth Thaumetopoea pityocampa

The 15- and 10-dimethylsila-analogues of (Z)-13-hexadecen-11-ynyl acetate, the main component of the female sex pheromone of the processionary moth Thaumetopoea pityocampa, were synthesized to evaluate the influence of the silicon atom on the biological activity.