603134-52-7

Basic information

• Product Name: 1,2-Benzenedicarboxylic acid, 5-methyl-3-[(1R)-1,2,2-trimethylcyclopentyl]-, dimethyl ester
• CAS NO: 603134-52-7
• Molecular Formula: C19H26O4
• Molecular Weight: 318.413
• Mol File: 603134-52-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,2-Benzenedicarboxylic acid, 5-methyl-3-[(1R)-1,2,2-trimethylcyclopentyl]-, dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Benzenedicarboxylic acid, 5-methyl-3-[(1R)-1,2,2-trimethylcyclopentyl]-, dimethyl ester(603134-52-7)
• EPA Substance Registry System: 1,2-Benzenedicarboxylic acid, 5-methyl-3-[(1R)-1,2,2-trimethylcyclopentyl]-, dimethyl ester(603134-52-7)

Safety Data

• Hazardous Substances Data: 603134-52-7(Hazardous Substances Data)

Upstream product

• 438626-02-9 2-methyl-4-(1',2',2'-trimethylcyclopentyl)-1,3-butadiene 
• 438626-00-7 1-hydroxymethyl-1,2,2-trimethylcyclopentane 
• 438626-01-8 1,2,2-trimethylcyclopentane-1-carboxaldehyde 
• 54812-11-2 methyl 1,2,2-trimethylcyclopentanecarboxylate 
• 603134-48-1 5-Methyl-3-((S)-1,2,2-trimethyl-cyclopentyl)-cyclohexa-1,4-diene-1,2-dicarboxylic acid dimethyl ester 
• 29606-94-8 (1S,3R)-3-(methoxycarbonyl)-2,2,3-trimethylcyclopentanecarboxylic acid 

Downstream Products

• 603134-53-8 5-Methyl-3-((R)-1,2,2-trimethyl-cyclopentyl)-phthalic acid 2-methyl ester 

Relevant articles and documents

Convenient route to enantiopure aryl cyclopentanes via Diels-Alder reaction of asymmetric dienes. Total synthesis of (+)-herbertene and (+)-cuparene

A general route for the synthesis of highly substituted aryl cyclopentanes has been developed involving Diels-Alder reaction of asymmetric dienes prepared from (+)-camphoric acid followed by aromatization of the resulting cyclohexene derivatives. Employing this protocol enantiospecific synthesis of (+)-herbertene and (+)-cuparene has been accomplished.