603137-30-0

Basic information

• Product Name: 3-Methyl-6-((S)-1,2,2-trimethyl-cyclopentyl)-cyclohexa-1,4-diene
• Synonyms: 3-Methyl-6-((S)-1,2,2-trimethyl-cyclopentyl)-cyclohexa-1,4-diene
• CAS NO: 603137-30-0
• Molecular Weight: 204.356
• Mol File: 603137-30-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Methyl-6-((S)-1,2,2-trimethyl-cyclopentyl)-cyclohexa-1,4-diene(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Methyl-6-((S)-1,2,2-trimethyl-cyclopentyl)-cyclohexa-1,4-diene(603137-30-0)
• EPA Substance Registry System: 3-Methyl-6-((S)-1,2,2-trimethyl-cyclopentyl)-cyclohexa-1,4-diene(603137-30-0)

Safety Data

• Hazardous Substances Data: 603137-30-0(Hazardous Substances Data)

Upstream product

• 108-31-6 maleic anhydride 
• 54812-11-2 methyl 1,2,2-trimethylcyclopentanecarboxylate 
• 29606-94-8 (1S,3R)-3-(methoxycarbonyl)-2,2,3-trimethylcyclopentanecarboxylic acid 
• 438626-01-8 1,2,2-trimethylcyclopentane-1-carboxaldehyde 
• 438626-00-7 1-hydroxymethyl-1,2,2-trimethylcyclopentane 

Downstream Products

• 16982-00-6 cuparene 

Relevant articles and documents

Convenient route to enantiopure aryl cyclopentanes via Diels-Alder reaction of asymmetric dienes. Total synthesis of (+)-herbertene and (+)-cuparene

A general route for the synthesis of highly substituted aryl cyclopentanes has been developed involving Diels-Alder reaction of asymmetric dienes prepared from (+)-camphoric acid followed by aromatization of the resulting cyclohexene derivatives. Employing this protocol enantiospecific synthesis of (+)-herbertene and (+)-cuparene has been accomplished.