60430-80-0Relevant articles and documents
Equilibrium acidities and homolytic bond dissociation enthalpies of the acidic C-H bonds in as-substituted triphenylarsonium and related cations
Cheng, Jin-Pei,Liu, Bo,Zhao, Yongyu,Zhang, Xian-Man
, p. 7072 - 7077 (2007/10/03)
Equilibrium acidities (P.KHAS) of As-fluorenyltriphenylarsonium, As-phenacyltriphenylarsonium, six As-(panz-substituted benzyDtriphenylarsonium [p-GC6H4CH2+AsPh3] (G = H, Me, CF3, CO2Me, CN, and N02), and six P-(para-substituted benzyl)tri(ra-butyl)phosphonium [p-GC6H4CH2+P(w-Bu)3] (G = H, Me, CF3, CO2Me, CN, and NO2) bromide salts, together with the oxidation potentials [SOX(A-)] of their conjugate bases (ylides) have been determined in dimethyl sulfoxide (DMSO) solution. Introduction of an a-triphenylarsonium (a-PhsAs+) group was found to increase the adjacent C-H bond acidities by 13-20 pK units (18-27 kcal/mol). The equilibrium acidities for the two series p-GC6H4CH2+AsPh3 andp-GC6H4CH2+P(n-Bu)3 cations were found to be nicely correlated with the Hammett er constants of the correspondingpara-substituents (G) (Figures 1 and 2). The homolytic bond dissociation enthalpies (BDEs) of the acidic C-H bonds determined by using eq 1 reveal that an a-PhsAs"1" group increases the BDE value of the adjacent acidic C-H bond by 2-5 kcal/mol, whereas the substituent effects for an a-Ph3P+ or a-(w-Bu)3Pf group was found to be dependent on the nature of the substituents attached to the a-carbon atom. Good linear correlations were obtained for the equilibrium acidities of As-(para-substituted benzyDtriphenylarsonium and P-(parasubstituted benzyl)tri(?-butyl)phosphonium cations with the oxidation potentials of their conjugate bases (ylides) as shown in Figures 3 and 4, respectively.