60514-15-0

Basic information

• Product Name: (o-CH₃C₆H₄)3SnBr
• Synonyms: (o-CH₃C₆H₄)3SnBr
• CAS NO: 60514-15-0
• Molecular Weight: 472.012
• Mol File: 60514-15-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (o-CH₃C₆H₄)3SnBr(CAS DataBase Reference)
• NIST Chemistry Reference: (o-CH₃C₆H₄)3SnBr(60514-15-0)
• EPA Substance Registry System: (o-CH₃C₆H₄)3SnBr(60514-15-0)

Safety Data

• Hazardous Substances Data: 60514-15-0(Hazardous Substances Data)

Upstream product

• 932-31-0 ortho-tolylmagnesium bromide 
• 10035-10-6 hydrogen bromide 
• 4583-39-5 tris(o-tolyl)tin chloride 
• 5728-01-8 tetra-o-tolyltin 

Downstream Products

• 1254-98-4 (o-CH₃C₆H₄)3SnC₆H₂-2,4,6-(CH₃)3 
• 51729-82-9 trichloro-2-tolylstannane 

Relevant articles and documents

Studies in aryltin chemistry. X 1. Synthesis and NMR spectra (119Sn and 13C) of some meta-and ortho-substituted tetra-and triaryltin compounds. The crystal and molecular structures of tris(m-tolyl)-and tris(3,5-dimethylphenyl) tin(IV) chloride

Several new tetra-aryltin compounds, Ar4Sn [Ar = 3,5-(CH3)2C6H3, 3,5-Z2C6H3, and m-ZC6H4 (Z = F, Cl)] and Ar3SnX [X = Cl, Br, I: Ar = 3,5-(CH3)2C6H3, m-and o-CH3OC6H4; X = Br; Ar = m-ZC6H4 (Z = F, Cl)] have been synthesized by literature methods and complete solution NMR data (119Sn, 13C) are reported for these and other meta-and ortho-substituted aryltins. Meta-substituents appear to exert electronic effects on chemical shifts and coupling constants, but for ortho-substituents steric effects appear to predominate. Crystal data show that meta-substituted Ar3SnX have trigonal unit cells in contrast to the monoclinic unit cells adopted by para-and ortho-substituted Ar3SnX. Complete crystal structures are reported for (m-CH3C6H4)3SnCl: R3, a= 14.9262(15), c = 7.3482(12)A, Z=3 and (3,5-(CH3)2C6H3)3SnCl: R3c, a = 15.779(8), c = 15.593(4)A, Z = 6. In both cases, all molecules have trigonal symmetry, the first such examples to be reported.