60633-78-5Relevant articles and documents
Selective detection of Hg(II) with benzothiazole-based fluorescent organic cation and the resultant complex as a ratiometric sensor for bromide in water
Singh, Amanpreet,Singh, Ajnesh,Singh, Narinder,Jang, Doo Ok
, p. 3535 - 3541 (2016)
A benzothiazole-based receptor conjugated with an imidazolium cation, receptor N1, was synthesized. Receptor N1 is capable of selectively binding Hg(II) in the presence of other metal ions in water, with a large enhancement in fluorescence intensity at 38
Design, synthesis, in silico and in vitro studies for new nitric oxide‐releasing indomethacin derivatives with 1,3,4‐oxadiazole‐2‐thiol scaffold
Sava, Alexandru,Buron, Frederic,Routier, Sylvain,Panainte, Alina,Bibire, Nela,Constantin, Sandra M?d?lina,Lupa?cu, Florentina Geanina,Foc?a, Alin Viorel,Profire, Lenu?a
, (2021/07/07)
Starting from indomethacin (IND), one of the most prescribed non‐steroidal anti‐inflammatory drugs (NSAIDs), new nitric oxide‐releasing indomethacin derivatives with 1,3,4‐oxadiazole‐ 2‐thiol scaffold (NO‐IND‐OXDs, 8a‐p) have been developed as a safer and
Iron-catalyzed protodehalogenation of alkyl and aryl halides using hydrosilanes
Pilli, Ramadevi,Balakrishnan, Venkadesh,Chandrasekaran, Revathi,Rasappan, Ramesh
supporting information, p. 1749 - 1753 (2019/02/20)
A simple and efficient iron-catalyzed protodehalogenation of alkyl and aryl halides using phenylhydrosilane is disclosed. The reaction utilizes FeCl3 without the requirement of ligands. Unactivated alkyl and aryl halides were successfully reduced in good yields; sterically hindered tertiary halides were also reduced including the less reactive chlorides. The scalability of this methodology was demonstrated by a gram-scale synthesis with a catalyst loading as low as 0.5 mol%. Notably, disproportionation of phenylsilane leads to diphenylsilane that further reduces the halides. Preliminary mechanistic studies revealed a non-radical pathway and the source of hydrogen is PhSiH3via deuterium labeling studies. Our methodology represents simplicity and provides a good alternative to typical tin, aluminum and boron hydride reagents.
