60669-38-7

Basic information

• Product Name: Benzene, 3-hexenyl-, (E)-
• CAS NO: 60669-38-7
• Molecular Formula: C12H16
• Molecular Weight: 160.259
• Mol File: 60669-38-7.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzene, 3-hexenyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 3-hexenyl-, (E)-(60669-38-7)
• EPA Substance Registry System: Benzene, 3-hexenyl-, (E)-(60669-38-7)

Safety Data

• Hazardous Substances Data: 60669-38-7(Hazardous Substances Data)

Upstream product

• 591-93-5 1,4-Pentadiene 
• 108-88-3 toluene 
• 72737-52-1 2-<(1-penten-3-yl)oxy>benzothiazole 
• 6921-34-2 benzylmagnesium chloride 
• 7484-37-9 (3-phenylpropyl)triphenylphosphonium bromide 
• 123-38-6 propionaldehyde 
• 592-47-2 3-hexene 
• 75456-62-1 (4-methoxybut-3-en-1-yl)benzene 
• 1338073-36-1 2-(1-cyclopropyl-3-phenylpropyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 83333-73-7 (E)-1-phenylhex-4-en-3-ol 

Relevant articles and documents

Dehalogenative Deuteration of Unactivated Alkyl Halides Using D2O as the Deuterium Source

The general dehalogenation of alkyl halides with zinc using D2O or H2O as a deuterium or hydrogen donor has been developed. The method provides an efficient and economic protocol for deuterium-labeled derivatives with a wide substrate scope under mild reaction conditions. Mechanistic studies indicated that a radical process is involved for the formation of organozinc intermediates. The facile hydrolysis of the organozinc intermediates provides the driving force for this transformation.

Synthesis of hydroxyphthioceranic acid using a traceless lithiation-borylation-protodeboronation strategy

In planning organic syntheses, disconnections are most often made adjacent to functional groups, which assist in C-C bond formation. For molecules devoid of obvious functional groups this approach presents a problem, and so functionalities must be installed temporarily and then removed. Here we present a traceless strategy for organic synthesis that uses a boronic ester as such a group in a one-pot lithiation-borylation-protodeboronation sequence. To realize this strategy, we developed a methodology for the protodeboronation of alkyl pinacol boronic esters that involves the formation of a boronate complex with a nucleophile followed by oxidation with Mn(OAc) 3 in the presence of the hydrogen-atom donor 4-tert-butylcatechol. Iterative lithiation-borylation- protodeboronation allows the coupling of smaller fragments to build-up long alkyl chains. We employed this strategy in the synthesis of hydroxyphthioceranic acid, a key component of the cell-wall lipid of the virulent Mycobacterium tuberculosis, in just 14 steps (longest linear sequence) with full stereocontrol.

α-Lithio quinuclidine N-oxide (Li-QNO): A new base for synthetic chemistry

α-Lithio quinuclidine N-oxide (Li-QNO) behaves as a strong non-nucleophilic base and an HMPA mimetic in a tandem process, in a range of synthetically useful reactions. The Royal Society of Chemistry 2006.