60669-39-8

Basic information

• Product Name: cyclohexane, 1-buten-1-yl-
• Synonyms: But-1-en-1-ylcyclohexane
• CAS NO: 60669-39-8
• Molecular Formula: C₁₀H₁₈
• Molecular Weight: 138.2499
• Mol File: 60669-39-8.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 176.739°C at 760 mmHg
• Flash Point: 47.051°C
• Density: 0.87g/cm³
• Vapor Pressure: 1.449mmHg at 25°C
• Refractive Index: 1.517
• CAS DataBase Reference: cyclohexane, 1-buten-1-yl-(CAS DataBase Reference)
• NIST Chemistry Reference: cyclohexane, 1-buten-1-yl-(60669-39-8)
• EPA Substance Registry System: cyclohexane, 1-buten-1-yl-(60669-39-8)

Safety Data

• Hazardous Substances Data: 60669-39-8(Hazardous Substances Data)

Upstream product

• 108-85-0 1-bromocyclohexane 
• 7623-11-2 2-chlorobutyryl chloride 
• 28832-55-5 2-Chlorobutanal 
• 931-50-0 cyclohexylmagnesium bromide 
• 1136238-60-2 C₁₃H₂₅O₄P 
• 75-16-1 methylmagnesium bromide 

Relevant articles and documents

Bidentate hydroxyalkyl NHC ligands for the copper-catalyzed asymmetric allylic substitution of allyl phosphates with grignard reagents

Demonstrating their potential: Bidentate alkoxy NHC ligands have been used in the copper-catalyzed asymmetric allylic alkylation of allyl phosphates with Grignard reagents (see scheme). The method provides access to tertiary and quaternary chiral centers with high regio- and enantioselectivity. The system is also applied to the synthesis of chiral E,E-dienes, a key structural motif prevalent in natural products. Copyright

Synthesis of Olefins from α-Chlorocarbonyl Compounds

Olefins or diolefins with the double bonds in predetermined positions are obtained in moderate to good yields by treatment of α-chlorocarbonyl compounds with Grignard reagents and lithium in a single process.