606937-97-7Relevant articles and documents
Total Synthesis of (±)-Isocembrene: A Tactic for both Diene Construction and Macrocycle Formation
Zhang, Fengzhi,Peng, Lizeng,Zhang, Tao,Mei, Tiansheng,Liu, Huawei,Li, Yulin
, p. 3761 - 3770 (2003)
The total synthesis of (±)-isocembrene 1, a naturally occurring cembrene diterpenoid, has been achieved via a unified, convergent and highly efficient strategy by imploying an intramolecular Stille sp2-sp 2 macrocyclization as the key step and it presents an ideal opportunity to extend the effectiveness of the tactic for both 1,3-diene construction and macrocycle formation.
