60706-24-3

Basic information

• Product Name: 2,6-DIPHENYLNAPHTHALENE
• Synonyms: 2,6-DIPHENYLNAPHTHALENE
• CAS NO: 60706-24-3
• Molecular Formula: C₂₂H₁₆
• Molecular Weight: 280.36
• Product Categories: Naphthalene derivatives
• Mol File: 60706-24-3.mol
• Article Data: 7

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2,6-DIPHENYLNAPHTHALENE(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6-DIPHENYLNAPHTHALENE(60706-24-3)
• EPA Substance Registry System: 2,6-DIPHENYLNAPHTHALENE(60706-24-3)

Safety Data

• Hazardous Substances Data: 60706-24-3(Hazardous Substances Data)

Usage

General Description

2,6-Diphenylnaphthalene is a polycyclic aromatic hydrocarbon consisting of a naphthalene core with two phenyl groups attached at the 2 and 6 positions. It is a white solid with a molecular formula of C22H16 and is insoluble in water, but soluble in organic solvents like benzene and ethanol. 2,6-Diphenylnaphthalene is primarily used as an intermediate in the production of various organic compounds, including dyes, pigments, and pharmaceuticals. It is also used in research and as a fluorescence standard in the laboratory. 2,6-DIPHENYLNAPHTHALENE poses some environmental and health risks as it is a potential contaminant of concern due to its persistence in the environment and its potential carcinogenic and toxic effects.

Upstream product

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Relevant articles and documents

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Nickel-Catalyzed Kumada Coupling of Boc-Activated Aromatic Amines via Nondirected Selective Aryl C-N Bond Cleavage

A nickel-catalyzed Kumada coupling of aniline derivatives was developed by selective cleavage of aryl C-N bonds under mild reaction conditions. Without preinstallation of an ortho directing group on anilines, the cross-coupling reactions of Boc-protected aromatic amines with aryl Grignard reagents afforded unsymmetric biaryls. Mechanistic studies by DFT calculations revealed that the nickel-mediated C-N bond cleavage is the rate-limiting step.

Cross-coupling of aryl/alkenyl silyl ethers with grignard reagents through nickel-catalyzed CO bond activation

CO activation and its application have drawn much attention since oxygen-based electrophiles are easily available, less toxic, and more environmentally benign. This letter presents systematically results on the Ni-catalyzed KumadaTamaoCorriu coupling based on siloxy arenes/alkenes, which provides a new strategy of silyl protection/CC bond formation sequence in organic synthesis.