60714-21-8

Basic information

• Product Name: 5‐(2,6,6‐trimethylcyclohex‐1‐en‐1‐yl)pentan‐2‐one
• Synonyms: 5‐(2,6,6‐trimethylcyclohex‐1‐en‐1‐yl)pentan‐2‐one
• CAS NO: 60714-21-8
• Molecular Weight: 208.344
• Mol File: 60714-21-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5‐(2,6,6‐trimethylcyclohex‐1‐en‐1‐yl)pentan‐2‐one(CAS DataBase Reference)
• NIST Chemistry Reference: 5‐(2,6,6‐trimethylcyclohex‐1‐en‐1‐yl)pentan‐2‐one(60714-21-8)
• EPA Substance Registry System: 5‐(2,6,6‐trimethylcyclohex‐1‐en‐1‐yl)pentan‐2‐one(60714-21-8)

Safety Data

• Hazardous Substances Data: 60714-21-8(Hazardous Substances Data)

Upstream product

• 6032-29-7 (+/-)-2-pentanol 
• 189633-81-6 2‐iodo‐1,3,3‐trimethylcyclohex‐1‐ene 
• 2408-37-9 2,2,6-trimethylcyclohexan-1-one 
• 54344-76-2 4-(2,6,6-trimethyl-cyclohex-1-enyl)-butyric acid 
• 917-54-4 methyllithium 

Downstream Products

• 5293-90-3 1,3,3-trimethyl-2-vinylcyclohexene 

Relevant articles and documents

Relay-Heck Cross-Coupling Between Alkenyl Halides and Unsaturated Alcohols in the Synthesis of Open-Chain Analogues of Musk Odorant Vulcanolide

Unactivated alkenyl iodides and bromides underwent an unprecedented palladium-catalyzed relay-Heck cross-coupling with a whole range of alkenols of different chain lengths linking the alkene and the alcohol, affording unsaturated aldehydes and ketones in moderate to good yields. In contrast, alkenyl triflates were not suitable partners for this reaction. This method allowed the preparation of open-chain analogues of the musk odorant Vulcanolide, several of which retained key olfactory properties of the parent molecule.