6075-62-3Relevant articles and documents
Enantioselective addition of terminal alkynes to isolated isoquinoline iminiums
Taylor, Alexander M.,Schreiber, Stuart L.
, p. 143 - 146 (2006)
(Chemical Equation Presented) The asymmetric, catalytic addition of terminal alkynes to discrete alkyliminium species in the presence of copper bromide, QUINAP ligand, and triethylamine is reported. The reaction proceeds in high yield and high enantiomeri
Diastereoselective synthesis of 1,2-disubstituted 2,3,4,5-tetrahydro1H-3- benzazepines by means of the Stevens rearrangement
Valpuesta, Maria,Ariza, Manuela,Diaz, Amelia,Suau, Rafael
experimental part, p. 4393 - 4401 (2010/10/04)
1,2-Disubstituted 2,3,4,5-tetrahydro-1H-3-benzazepines were conveniently obtained by making use of the regio- and diastereoselective Stevens rearrangement of the corresponding isoquinolinium salts with 1,8-diazabicyclo[5.4.0]undec-7-ene in acetonitrile, T
Reactions of N-quaternary 1-phenyl-3,4-dihydroisoquinolinium compounds with nucleophiles - Products and their isomerism - Part 1
Moehrle,Breves
, p. 181 - 191 (2007/10/03)
Variously substituted 1-phenyl-3,4-dihydroisoquinolinium compounds were prepared, in order to study their reactions with hydroxide ions concerning ring-chain isomerism of their products. Thereby was observed a dependence on the electrophilic properties of