608-44-6Relevant articles and documents
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Gebauer,Fuelnegg,Malnic
, p. 403 (1926)
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(E)-4-(4-(3-(2-fluoro-5-(trifluoromethyl)phenyl)acryloyl)phenoxy)Substituted Co(II)and Cu(II)phthalocyanines and their catalytic activities on the oxidation of phenols
Saka, Ece Tugba,Kahriman, Nuran
supporting information, p. 48 - 54 (2019/06/05)
Phenols from various man-made activities pose threats to public health and aquatic ecosystems. A number of technologies (e.g., adsorption, oxidation, and biological methods)have been proposed and tested to remove phenolic compounds from different sources. Among these technologies, oxidation process is considered one of the most efficient tools for abating phenolic compounds because of low cost, easy scalability, and ecofriendly production. In this work, we aim to synthesize and characterize potential catalysts (Co(II)and Cu(II)phthalocyanines 6 and 7)for phenolic compounds oxidation. Different parameters influenced the oxidation process were determined and phenolic compounds oxidize to the less harmful products with high conversion and yield in the presence of Co(II)and Cu(II)phthalocyanine catalysts.
Cycloacylation of chloro-substituted hydroquinone dimethyl ethers with dichloromaleic anhydride
Novikov,Balaneva,Shestak,Anufriev, V. Ph.,Glazunov
, p. 993 - 1003 (2017/01/11)
Under the drastic conditions of Zahn—Ochwat cycloacylation of 2-chloroand 2,3-dichlorohydroquinones with dichloromaleic anhydride (a melt of anhydrous AlCl3 and NaCl, 185—195 °C), the substrates undergo various degrees of disproportionation, which reduces the yields of the target triand tetrachloronaphthazarins. Quantum chemical calculations showed that the cycloacylation in question proceeds as a double aromatic electrophilic substitution of the vicinal protons with the corresponding oxocarbenium ions (acylium cations).