60835-69-0Relevant articles and documents
Preparation, photophysical, electrochemical, and ion-binding properties of Ru(II) polypyridyl complexes containing a crown ether unit
Cheng, Feixiang,Tang, Ning,Chen, Jishu,Wang, Fan,Chen, Longhai
, p. 923 - 929 (2011)
Two polypyridyl ligands, 4'-(4,5-diazafluoren-9-ylimino)benzo-15-crown-5 (L1) and 4'-(4,5-diazafluoren-9-ylimino)benzo-12-crown-4 (L 2), and their Ru(II) complexes [(bpy)2RuL](PF 6)2 and [(bpy)2RuL2](PF 6)2, respectively, have been synthesized and characterized. The two complexes display metal-to-ligand charge transfer absorptions at around 444 nm in CH3CN solution at r. t. and emission at around 573 nm in an EtOH-MeOH (4:1, v/v) glassy matrix at 77 K. Electrochemical studies of the complexes show one Ru(II)-centered oxidation at around 1.33 V and three ligandcentered reductions. The binding ability of the complexes with Na+ and Li+ has been investigated by UV/Vis absorption and emission spectroscopy and electrochemical titrations. Addition of Na+ and Li+ to solutions of the complexes results in a progressive quenching of the emission, a hyperchromic effect of the UV/Vis absorption, and a progressive cathodal shift of the Ru(II)-centered E 1/2 potential. The stability constants for the stoichiometric 1:1 ratio of the complexes and the cations have been obtained by UV/Vis absorption titration.
Chalcogen Bond Mediated Enhancement of Cooperative Ion-Pair Recognition
Bunchuay, Thanthapatra,Docker, Andrew,Eiamprasert, Utt,Surawatanawong, Panida,Brown, Asha,Beer, Paul D.
, p. 12007 - 12012 (2020)
A series of heteroditopic receptors containing halogen bond (XB) and unprecedented chalcogen bond (ChB) donors integrated into a 3,5-bis-triazole pyridine structure covalently linked to benzo-15-crown-5 ether motifs exhibit remarkable cooperative recognition of halide anions. Multi-nuclear 1H, 13C, 125Te and 19F NMR, ion pair binding investigations reveal sodium cation–benzo-crown ether binding dramatically enhances the recognition of bromide and iodide halide anions, with the chalcogen bonding heteroditopic receptor notably displaying the largest enhancement of halide binding strength of over two hundred-fold, in comparison to the halogen bonding and hydrogen bonding heteroditopic receptor analogues. DFT calculations suggest crown ether sodium cation complexation induces a polarisation of the sigma hole of ChB and XB heteroditopic receptor donors as a significant contribution to the origin of the unique cooperativity exhibited by these systems.
Production of macrocyclic polyether benzo-15-crown-5 and its functional derivatives
Glushko, Valentina N.,Sadovskaya, Natalya Yu.,Kozhuhov, Vadim I.,Blokhina, Lidiya I.,Antropova, Irina A.,Petina, Ekaterina S.,Retiviov, Vasiliy M.,Melnikova, Ekaterina Yu.
, p. 1689 - 1697 (2017/10/27)
Study of interaction between catechol and tetraethylene glycol dichloride in the n-butanol media, resulting with benzo-15-crown-5 production. Production of nitro- and amino-derivatives of benzo-15-crown-5. Determination of their thermogravimetric characteristics.
Supramolecular assembly of isocyanorhodium(i) complexes: An interplay of rhodium(i)···rhodium(i) interactions, hydrophobic-hydrophobic interactions, and host-guest chemistry
Chan, Alan Kwun-Wa,Wong, Keith Man-Chung,Yam, Vivian Wing-Wah
, p. 6920 - 6931 (2015/06/16)
A series of tetrakis(isocyano)rhodium(I) complexes with different chain lengths of alkyl substituents has been found to exhibit a strong tendency toward solution state aggregation upon altering the concentration, temperature and solvent composition. Temperature- and solvent-dependent UV-vis absorption studies have been performed, and the data have been analyzed using the aggregation model to elucidate the growth mechanism. The aggregation is found to involve extensive Rh(I)···Rh(I) interactions that are synergistically assisted by hydrophobic-hydrophobic interactions to give a rainbow array of solution aggregate colors. It is noted that the presence of three long alkyl substituents is crucial for the observed cooperativity in the aggregation. Molecular assemblies in the form of nanoplates and nanovesicles have been observed in the hexane-dichloromethane solvent mixtures, arising from the different formation mechanisms based on the alkyl chain length of the complexes. Benzo-15-crown-5 moieties have been incorporated for selective potassium ion binding to induce dimer formation and drastic color changes, rendering the system as potential colorimetric and luminescent cation sensors and as building blocks for ion-controlled supramolecular assembly.