610272-48-5

Basic information

• Product Name: 1-[((E)-3-bromoallyloxy)methyl]benzene
• Synonyms: 1-[((E)-3-bromoallyloxy)methyl]benzene
• CAS NO: 610272-48-5
• Molecular Weight: 227.101
• Mol File: 610272-48-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-[((E)-3-bromoallyloxy)methyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[((E)-3-bromoallyloxy)methyl]benzene(610272-48-5)
• EPA Substance Registry System: 1-[((E)-3-bromoallyloxy)methyl]benzene(610272-48-5)

Safety Data

• Hazardous Substances Data: 610272-48-5(Hazardous Substances Data)

Upstream product

• 37428-55-0 (E)-3-bromoprop-2-en-1-ol 
• 100-39-0 benzyl bromide 

Downstream Products

• 610272-55-4 thiocarbonic acid O-(3-benzyloxy-2-tert-butoxycarbonylamino-1-trifluoromethyl-propyl) ester O-phenyl ester 
• 610272-64-5 thiocarbonic acid O-(3-benzyloxy-2-tert-butoxycarbonylamino-1-trifluoromethyl-propyl) ester O-phenyl ester 
• 610272-53-2 (2R,3R)-1-benzyloxy-2-(tert-butoxycarbonyl)amino-4,4,4-trifluorobutan-3-ol 
• 610272-63-4 (2S,3S)-1-benzyloxy-2-(tert-butoxycarbonyl)amino-4,4,4-trifluorobutan-3-ol 
• 610272-56-5 (2S)-1-benzyloxy-2-(tert-butoxycarbonyl)amino-4,4,4-trifluorobutane 
• 610272-65-6 (2R)-1-benzyloxy-2-(tert-butoxycarbonyl)amino-4,4,4-trifluorobutane 
• 610272-59-8 (3R,4S)-3-benzyloxymethyl-4-trifluoromethyl-2,2-dioxo-1,3,2-dioxathiolane 
• 610272-50-9 (3S,4R)-3-benzyloxymethyl-4-trifluoromethyl-2,2-dioxo-1,3,2-dioxathiolane 
• 610272-58-7 (2R,3S)-1-benzyloxy-4,4,4-trifluoro-2,3-butanediol 
• 610272-49-6 (2S,3R)-1-benzyloxy-4,4,4-trifluoro-2,3-butanediol 
• 610272-60-1 (2S,3S)-1-benzyloxy-2-azido-4,4,4-trifluorobutan-3-ol 
• 610272-51-0 (2R,3R)-1-benzyloxy-2-azido-4,4,4-trifluorobutan-3-ol 
• 610272-47-4 (E)-(((4,4,4-trifluorobut-2-en-1-yl)oxy)methyl)benzene 
• 194146-29-7 (4S,5S,2E)-5-amino-N-diphenylmethylene-1-O-benzyl-2-hexen-1,4-diol 

Relevant articles and documents

Asymmetric synthesis of both enantiomers of anti-4,4,4-trifluorothreonine and 2-amino-4,4,4-trifluorobutanoic acid

A short and efficient enantio selective synthesis of both enantiomers of anti-4,4,4-trifluorothreonine and 2-amino-4,4,4-trifluorobutanoic acid was successfully developed. Trifluoromethylation of benzyl-protected bromoalkene 4 provided key intermediate trifluoromethylated transdi-substituted alkene 2 in good yield. The sequence then involved Sharpless asymmetric dihydroxylation, nucleophilic opening of cyclic sulfate with NaN3, palladium-catalyzed selective hydrogenation, and oxidation.